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Merck

148938

Sigma-Aldrich

2-碘丙烷

contains copper as stabilizer, 99%

别名:

异丙基碘

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About This Item

线性分子式:
(CH3)2CHI
CAS号:
分子量:
169.99
Beilstein:
1098244
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

品質等級

化驗

99%

形狀

liquid

包含

copper as stabilizer

折射率

n20/D 1.498 (lit.)

bp

88-90 °C (lit.)

mp

−90 °C (lit.)

密度

1.703 g/mL at 25 °C (lit.)

SMILES 字串

CC(C)I

InChI

1S/C3H7I/c1-3(2)4/h3H,1-2H3

InChI 密鑰

FMKOJHQHASLBPH-UHFFFAOYSA-N

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一般說明

2-碘丙烷是一种有机碘化合物。它通常用作均裂和异裂烷基化剂,用于制备 α-异丙氧基亚甲基保护基团。此外,它还作为硫代碳酸盐转化为烯烃的中间体。

應用

2-碘丙烷(异丙基碘)被用于制备丁酸和异丁酸

2-碘丙烷被用作烷基化试剂将酚类、醇类、肟类、羧酸和杂原子化合物(吲哚、吡啶、嘌呤、四唑、吡唑和胺)转化为对应产物。

象形圖

FlameExclamation mark

訊號詞

Warning

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

107.6 °F - closed cup

閃點(°C)

42 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Joe Rashan et al.
Journal of AOAC International, 86(4), 694-702 (2003-09-26)
An alternative liquid chromatographic (LC) method was developed and validated for the simultaneous determination of methoxyl and 2-hydroxypropoxyl substituents in hypromellose and hypromellose acetate succinate. The method uses the hydriodic acid cleavage reaction, catalyzed by adipic acid, of the substituted
Timur Coskun et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(21), 6840-6844 (2013-03-29)
Glycerol is converted to a mixture of butyric and isobutyric acid by rhodium- or iridium-catalysed carbonylation using HI as the co-catalyst. The initial reaction of glycerol with HI results in several intermediates that lead to isopropyl iodide, which upon carbonylation
2-Iodopropane
Wilson PD and Hilmey DG
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
John J Orlando et al.
The journal of physical chemistry. A, 109(30), 6659-6675 (2006-07-13)
The reaction of Cl atoms with iodoethane has been studied via a combination of laser flash photolysis/resonance fluorescence (LFP-RF), environmental chamber/Fourier transform (FT)IR, and quantum chemical techniques. Above 330 K, the flash photolysis data indicate that the reaction proceeds predominantly
W Kenealy et al.
Journal of bacteriology, 146(1), 133-140 (1981-04-01)
Iodopropane inhibited cell growth and methane production when Methanobacterium thermoautotrophicum, Methanobacterium formicicum, and Methanosarcina barkeri were cultured on H2-CO2. Iodopropane (40 microM) inhibited methanogenesis (30%) and growth (80%) when M. barkeri was cultured mixotrophically on H2-CO2-methanol. The addition of acetate

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