02615

(乙氧基羰基甲基)三苯基氯化膦

technical, ≥90% (AT)

• 别名: (2-Ethoxy-2-oxoethyl)triphenylphosphonium chloride
• 线性分子式: CH₃CH₂OCOCH₂P(Cl)(C₆H₅)₃
• CAS号: 17577-28-5
• 分子量: 384.84
• Beilstein: 3924139
• EC號碼: 241-548-2
• MDL號碼: MFCD00011746
• 分類程式碼代碼: 12352108
• PubChem物質ID: 24845340
• NACRES: NA.22

属性

• 等級: technical
• 化驗: ≥90% (AT)
• 反應適用性: reaction type: C-C Bond Formation
• mp: 120-123 °C (dec.); 120-123 °C (lit.)
• 官能基: ester; phosphine
• 儲存溫度: 2-8°C
• SMILES 字串: [Cl-].CCOC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3
• InChI: 1S/C22H22O2P.ClH/c1-2-24-22(23)18-25(19-12-6-3-7-13-19,20-14-8-4-9-15-20)21-16-10-5-11-17-21;/h3-17H,2,18H2,1H3;1H/q+1;/p-1
• InChI 密鑰: DJGHVEPNEJKZBF-UHFFFAOYSA-M

说明

應用

Reactant for:

• Preparation of disubstituted tetrahydrofurans as selective serotonin re-uptake inhibitors for the treatment of depression
• Ring-opening reactions with Wittig reagents
• Enantioselective total synthesis of the phytotoxic lactone herbarumin III via Keck′s asymmetric allylation and Sharpless epoxidation
• Synthesis of fluorobenzofurans via microwave-assisted tandem intramolecular Wittig and Claisen rearrangement reactions
• Preparation of phosphonium derivatives of coumarin

其他說明

制备 Wittig 试剂的原料

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves