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248401

Sigma-Aldrich

Magnesium methyl carbonate solution

2.0 M in DMF

Synonym(s):

MMC, Methoxymagnesium methyl carbonate, Methyl methoxymagnesium carbonate, Stile’s reagent

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About This Item

Linear Formula:
CH3OMgOCO2CH3
CAS Number:
4861-79-4
Molecular Weight:
130.38
Beilstein:
4342967
MDL number:
MFCD00008418
UNSPSC Code:
12352302
PubChem Substance ID:
24854927
NACRES:
NA.22

form

liquid

Quality Level

200

concentration

2.0 M in DMF

density

1.103 g/mL at 25 °C

SMILES string

CO[Mg]OC(=O)OC

InChI

1S/C2H4O3.CH3O.Mg/c1-5-2(3)4;1-2;/h1H3,(H,3,4);1H3;/q;-1;+2/p-1

InChI key

PNVKCUSCADAAMP-UHFFFAOYSA-M

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General description

Magnesium methyl carbonate is also known as Stile′s reagent. It is used as a carboxylating agent for the α-carboxylation of nitroalkanes, ketones, lactones, hydantoins, and phenols.

Signal Word

Danger-Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B - Skin Irrit. 2

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

136.4 °F - closed cup

Flash Point(C)

58 °C - closed cup

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Chen Ling et al.
Cell discovery, 2, 16047-16047 (2017-01-07)
The recruitment of FANCM, a conserved DNA translocase and key component of several DNA repair protein complexes, to replication forks stalled by DNA interstrand crosslinks (ICLs) is a step upstream of the Fanconi anemia (FA) repair and replication traverse pathways
Aleksandra Wlaź et al.
Acta ophthalmologica, 97(6), e817-e826 (2019-03-30)
To compare the efficacy and safety of collagen matrix implant (Ologen® ; OLO) with mitomycin C (MMC) in phacotrabeculectomy. Prospective, single-centre, nonblinded, randomized controlled trial. A total of 53 eyes of 45 patients were enrolled in the study protocol with
Akbar Adjie Pratama et al.
Scientific reports, 7(1), 9156-9156 (2017-08-24)
Bacteriophages constitute key gene transfer agents in many bacteria. Specifically, they may confer gene mobility to Paraburkholderia spp. that dwells in soil and the mycosphere. In this study, we first screened mycosphere and bulk soils for phages able to produce
De-Sheng Song et al.
Medicine, 98(25), e16094-e16094 (2019-06-25)
To evaluate the efficacy and safety of trabeculectomy (Trab) with mitomycin-C (MMC) versus Trab with implant. Studies published in different languages were retrieved by systematically searching Embase, PubMed, Cochrane library, China Biology Medicine disc, and Google Scholar from 1966 to
Sebastiano Di Bucchianico et al.
Particle and fibre toxicology, 15(1), 32-32 (2018-07-19)
Genotoxicity is an important toxicological endpoint due to the link to diseases such as cancer. Therefore, an increased understanding regarding genotoxicity and underlying mechanisms is needed for assessing the risk with exposure to nanoparticles (NPs). The aim of this study
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