If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
271004
Acetonitrilo
99.8%, anhydrous, suitable for solid phase extraction (SPE)
Sinónimos:
ACN, Cianometano, Cianuro de metilo, Nitrilo de etilo
About This Item
Productos recomendados
Nombre del producto
Acetonitrilo, anhydrous, 99.8%
grade
anhydrous
Quality Level
vapor density
1.41 (vs air)
vapor pressure
72.8 mmHg ( 20 °C)
assay
99.8%
form
liquid
autoignition temp.
973 °F
expl. lim.
16 %
technique(s)
solid phase extraction (SPE): suitable
impurities
<0.001% water
<0.005% water (100 mL pkg)
evapn. residue
<0.0005%
color
colorless
refractive index
n20/D 1.344 (lit.)
bp
81-82 °C (lit.)
mp
−45 °C (lit.)
solubility
water: soluble (completely)
density
0.786 g/mL at 25 °C (lit.)
format
neat
SMILES string
CC#N
InChI
1S/C2H3N/c1-2-3/h1H3
InChI key
WEVYAHXRMPXWCK-UHFFFAOYSA-N
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General description
Application
- 1,2-acidoalcoholes y 1,2-acidoaminas mediante la apertura del anillo de los epóxidos asistida con cloruro de cerio(III) y de las aziridinas con acida sódica.[3]
- Indolinonas que contienen ciano por arilalquilación oxidativa de olefinas en presencia del catalizador paladio.[4]
También puede utilizarse como reactivo para sintetizar:
- Bis (difenilfosfino) acetonitrilo reaccionando con n-butillitio y luego con clorodifenilfosfina.[5]
- β-Acetamido cetonas mediante reacción de acoplamiento con cetonas o cetoésteres y aldehídos en presencia de cloruro de cobalto(II).[6]
Packaging
also commonly purchased with this product
related product
suggested gloves for splash protection
signalword
Danger
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 2
Storage Class
3 - Flammable liquids
wgk_germany
WGK 2
flash_point_f
35.6 °F - closed cup
flash_point_c
2.0 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Substances are said to be miscible in one another if they dissolve to form a uniform solution. Bookmark or download our miscibility table for common lab solvents.
Substances are said to be miscible in one another if they dissolve to form a uniform solution. Bookmark or download our miscibility table for common lab solvents.
Se dice que las sustancias son miscibles entre sí si se disuelven hasta formar una disolución uniforme. Marque o descargue nuestra tabla de miscibilidad para los disolventes comunes del laboratorio.
Se dice que las sustancias son miscibles entre sí si se disuelven hasta formar una disolución uniforme. Marque o descargue nuestra tabla de miscibilidad para los disolventes comunes del laboratorio.
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How can I determine the shelf life / expiration / retest date of this product?
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Helpful?
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How is shipping temperature determined? And how is it related to the product storage temperature?
1 answer-
Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
Helpful?
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Hi! By which method is the acetonitrile dried? Is molecular sieve used? Thanks!
1 answer-
Unfortunately, the manufacturing process of this product is proprietary. If necessary, molecular sieves can help to further dry the product before use.
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Hey, my name is Mohammad. We tried to develop sensor ro detect heavy metals. And I fond some peaks in the solution when I added acn 99.8% and I want to know if there is heavy metals and which metals?
1 answer-
Unfortunately, this product is not tested for heavy metals. Should this be a critical issue for the specific application, see product 900667. This product is tested for trace metals and may be a better option. See the link below to review a sample Certificate of Analysis:
https://www.sigmaaldrich.com/certificates/sapfs/PROD/sap/certificate_pdfs/COFA/Q14/900667-BULKSHBR1056.pdfHelpful?
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