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Merck

935646

Sigma-Aldrich

Ethylene sulfate

new
greener alternative

≥99%, anhydrous, battery grade

Sinónimos:

1,3,2-Dioxathiolane 2,2-dioxide, DTD

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About This Item

Fórmula empírica (notación de Hill):
C2H4O4S
Número de CAS:
Peso molecular:
124.12
MDL number:
UNSPSC Code:
12352005

grade

anhydrous
battery grade

Quality Level

assay

≥99%

form

powder

greener alternative product characteristics

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Learn more about the Principles of Green Chemistry.

sustainability

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impurities

≤750 ppm (H2O)

bp

231 °C

mp

95-97 °C (lit.)

application(s)

battery manufacturing

greener alternative category

storage temp.

2-8°C

SMILES string

O=S1(=O)OCCO1

InChI

1S/C2H4O4S/c3-7(4)5-1-2-6-7/h1-2H2

InChI key

ZPFAVCIQZKRBGF-UHFFFAOYSA-N

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General description

Ethylene sulfate (DTD) is a polar cyclic sulfate ester. It is a white powder that is soluble in many of the polar organic solvents used in battery applications, including carbonates. Our battery grade ethylene sulfate is differentiated by its high purity, low trace water content, and low trace acid content, which avoid unwanted chemical reactions with the anode and increase capacity, safety, and life span in batteries

Application

Ethylene sulfate has a range of industrial applications. Our anhydrous battery grade ethylene sulfate is primarily used as an electrolyte additive to extend the lifetime of lithium-ion batteries and sodium-ion batteries.[,] Ethylene sulfate helps to improve the formation of a stable solid-electrolyte interphase (SEI) on the surface of the anode material, which can prevent reaction between the anode and the electrolyte, leading to better battery lifespan and more stable impedance across the interphase.[] DTD is often used in conjunction with other additives. One of the best-performing electrolyte formulations for graphite cells is a 1.0 M LiPF6 in a carbonate blend with 1% DTD and 2%VC.[,]

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Referencia del producto
Descripción
Precios

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - Skin Sens. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Visite la Librería de documentos

Optimizing Electrolyte Additive Loadings in NMC532/Graphite Cells: Vinylene Carbonate and Ethylene Sulfate
Taskovic T, et al.
Journal of the Electrochemical Society, 168, 010514-010514 (2021)
A Wide Range of Testing Results on an Excellent Lithium-Ion Cell Chemistry to be used as Benchmarks for New Battery Technologies
Jessie E, et al.
Journal of the Electrochemical Society, 166, A3031-A3031 (2019)
Ethylene sulfate as film formation additive to improve the compatibility of graphite electrode for lithium-ion battery
Xuecheng L, et al.
Ionics, 20, 795-801 (2014)
Effect of Sulfate Electrolyte Additives on LiNi1/3Mn1/3Co1/3O2/Graphite Pouch Cell Lifetime: Correlation between XPS Surface Studies and Electrochemical Test Results
Madec L, et al.
The Journal of Physical Chemistry C, 118, 29608-29622 (2014)
Comparative study of 1,3-propane sultone, prop-1-ene-1,3-sultone and ethylene sulfate as film-forming additives for sodium ion batteries
Zhang Q, et al.
Journal of Power Sources, 541, 231726-231726 (2022)

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