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733202

Sigma-Aldrich

cis-Dichlorobis(2,2′-bipyridine)ruthenium(II)

97%

Synonym(s):

cis-Bis(2,2′-bipyridine)dichlororuthenium(II) hydrate, cis-Ru(bpy)2Cl2.xH2O

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About This Item

Empirical Formula (Hill Notation):
C20H16Cl2N4Ru · xH2O
CAS Number:
Molecular Weight:
484.34 (anhydrous basis)
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

form

powder

reaction suitability

core: ruthenium
reagent type: catalyst

mp

475.2-493.3

SMILES string

[H]O[H].Cl[Ru]Cl.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4

InChI

1S/2C10H8N2.2ClH.H2O.Ru/c2*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;;/h2*1-8H;2*1H;1H2;/q;;;;;+2/p-2

InChI key

XBOQABVNRXVAKI-UHFFFAOYSA-L

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Application

cis-Dichlorobis(2,2′-bipyridine)ruthenium(II) can be used in synthesizing a variety of ruthenium complexes such as ruthenium(II) complex that can modify the surface of gold nanoparticles for the cysteine detection by selective luminescence. It can also be used in the preparation of ruthenium complexes to design photochromic molecular switches and self-assembling supramolecular systems.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Simple and selective sensing of cysteine using gold nanoparticles modified by Ruthenium (II) complexes.
Li M J, et al.
Journal of Nanoscience and Nanotechnology, 11(4), 3578-3585 (2011)
Femtosecond isomerization in a photochromic molecular switch.
Mockus N V, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 120(8), 1480-1483 (2008)
Photoinduced electron transfer in a triad that can be assembled/disassembled by two different external inputs. Toward molecular-level electrical extension cables.
Ballardini R, et al.
Journal of the American Chemical Society, 124(43), 12786-12795 (2002)

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