Skip to Content
Merck
All Photos(2)

Key Documents

686026

Sigma-Aldrich

Lithium borohydride

greener alternative

hydrogen-storage grade, ≥90%

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
LiBH4
CAS Number:
Molecular Weight:
21.78
EC Number:
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

grade

hydrogen-storage grade

Quality Level

Assay

≥90%

form

crystals

reaction suitability

reagent type: reductant

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

275 °C (dec.)

density

0.666 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

[Li+].[BH4-]

InChI

1S/BH4.Li/h1H4;/q-1;+1

InChI key

UUKMSDRCXNLYOO-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Lithium borohydride (LiBH4) is a complex hydride with a high hydrogen density. It is a strong reducing agent and an electrode material. It has a high gravimetric (18.4 wt%) and volumetric (121 kg/m3) hydrogen storage capacities. It can also be used in lithium-ion batteries.

Analysis Note

Hydrogen content, XRD plots and metal purity data are available upon request.

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B - Water-react 1

Storage Class Code

4.3 - Hazardous materials which set free flammable gases upon contact with water

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Nanoconfined 2LiBH4-MgH2-TiCl3 in carbon aerogel scaffold for reversible hydrogen storage
Gosalawit-Utke R, et al.
International Journal of Hydrogen Energy, 38(8), 3275-3282 (2013)
Hydrogen storage properties of modified lithium borohydrides
Au M, et al.
Journal of alloys and compounds, 462(1-2), 303-309 (2008)
Effects of intermediate layer on interfacial resistance for all-solid-state lithium batteries using lithium borohydride
Takahashi K, et al.
Solid State Ionics, 262, 179-182 (2014)
Mita Dasog et al.
Chemical communications (Cambridge, England), 47(30), 8569-8571 (2011-06-28)
In the presence of large excesses of borohydride salts, gold monolayer protected-clusters can be grown to larger sizes simply by controlling the amount of reducing agent added to smaller clusters. In addition, gold monolayer clusters can be used as catalysts
Sumalee Supothina et al.
The Journal of antibiotics, 57(11), 732-738 (2005-02-17)
Optimal fermentation conditions for enniatin production using the entomopathogenic fungus Verticillium hemipterigenum BCC 1449 have been investigated. Among various liquid media tested, highest efficiency of enniatin production was achieved by fermentation in yeast extract sucrose. Application of this condition to

Articles

An article about metal borohydrides as hydrogen storage materials

Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.

Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.

Solid-state lithium fast-ion conductors are crucial for safer, high-energy-density all-solid-state batteries, addressing conventional battery limitations.

See All

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service