590711

4-Chloro-2-methylaniline

98%

• Synonym(s): 2-Amino-5-chlorotoluene, 4-Chloro-o-toluidine
• Linear Formula: ClC₆H₃(CH₃)NH₂
• CAS Number: 95-69-2
• Molecular Weight: 141.60
• Beilstein: 878505
• EC Number: 202-441-6
• MDL number: MFCD00007842
• UNSPSC Code: 12352100
• PubChem Substance ID: 24881294
• NACRES: NA.22

Properties

• Assay: 98%
• form: solid
• refractive index: n20/D 1.583 (lit.)
• bp: 241 °C (lit.)
• mp: 24-27 °C (lit.)
• density: 1.19 g/mL at 25 °C (lit.)
• functional group: chloro
• SMILES string: Cc1cc(Cl)ccc1N
• InChI: 1S/C7H8ClN/c1-5-4-6(8)2-3-7(5)9/h2-4H,9H2,1H3
• InChI key: CXNVOWPRHWWCQR-UHFFFAOYSA-N

Description

Application

4-Chloro-2-methylaniline may be used in the synthesis of the following:

• 2,8-dichloro-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f]-diazocine via reaction with paraformaldehyde in toluene
• N-allylated derivative via palladium-catalyzed selective monoallylation with allyl alcohol
• N-(4-chloro-2-methylphenyl)benzamide via reaction with benzoyl chloride

Safety Information

• Pictograms: GHS06,GHS08,GHS09
• Signal Word: Danger
• Hazard Statements: H301 + H311 + H331,H341,H350,H410
• Precautionary Statements: P202 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P304 + P340 + P311
• Hazard Classifications: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Muta. 2
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point(F): 255.2 °F - closed cup
• Flash Point(C): 124 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves