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Quality Level
Assay
99%
form
liquid
refractive index
n20/D 1.443 (lit.)
bp
42 °C/115 mmHg (lit.)
density
0.91 g/mL at 25 °C (lit.)
SMILES string
Cc1ccoc1C
InChI
1S/C6H8O/c1-5-3-4-7-6(5)2/h3-4H,1-2H3
InChI key
FJSKXQVRKZTKSI-UHFFFAOYSA-N
General description
2,3-Dimethylfuran is a methyl substituted furan. The gas-phase rate constant determined by the relative rate method for the reaction of 2,3-dimethylfuran with NO3 radical was found to be (5.83 ± 0.46)×10-11 and with OH radical was (12.6 ± 0.4)×10-11 (in units of cm3 molecule-1 s-1). It is reported to be formed by the cyclization of (Z)-3-methylpent-2-en-4-yn-1-ol by various methods.
Application
2,3-Dimethylfuran may be used in the synthesis of 2,9-dioxabicyclo[3.3.1]nonane.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Flam. Liq. 2
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
30.2 °F - closed cup
Flash Point(C)
-1 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Gas-phase rate constants for the reaction of NO3 radicals with furan and methyl-substituted furans.
Chemical Physics Letters, 256(6), 679-683 (1996)
Benzimidazole, Benzothiazole and Benzoxazole Ruthenium (II) Complexes; Catalytic Synthesis of 2,3-Dimethylfuran.
European Journal of Organic Chemistry, 2000(1), 29-32 (2000)
Palladium-catalyzed cycloisomerization of (Z)-enynols into furans using green solvents: glycerol vs. water.
Green Chemistry, 12(9), 1552-1555 (2010)
Synthesis and reactivity studies of palladium (ii) complexes containing the N-phosphorylated iminophosphorane-phosphine ligands Ph2PCH2P{=NP (=O)(OR)2} Ph2 (R= Et, Ph): application to the catalytic synthesis of 2, 3-dimethylfuran.
Dalton Transactions, 47, 5593-5604 (2006)
Synthesis of a water-soluble carbene complex and its use as catalyst for the synthesis of 2,3-dimethylfuran.
Journal of Organometallic Chemistry, 633(1), 27-32 (2001)
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