736236
2-Cyanopropan-2-yl N-methyl-N-(pyridin-4-yl)carbamodithioate
97% (HPLC)
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About This Item
Empirical Formula (Hill Notation):
C11H13N3S2
CAS Number:
Molecular Weight:
251.37
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.23
Recommended Products
Quality Level
Assay
97% (HPLC)
form
solid
mp
97-102 °C
storage temp.
2-8°C
SMILES string
CN(C(=S)SC(C)(C)C#N)c1ccncc1
InChI
1S/C11H13N3S2/c1-11(2,8-12)16-10(15)14(3)9-4-6-13-7-5-9/h4-7H,1-3H3
InChI key
PYVIBYAVTHICFS-UHFFFAOYSA-N
Application
Switchable RAFT agent for controlled radical polymerization. The neutral form is well-suited for polymerization of vinyl esters and vinyl amides (LAMs), and the protonated form is well-suited for styrenes acrylates and methacrylates (MAMs). Chain Transfer Agent (CTA)
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Resp. Sens. 1 - Skin Sens. 1
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being
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