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About This Item
Linear Formula:
(ClCF2CO)2O
CAS Number:
Molecular Weight:
242.94
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
98%
form
liquid
refractive index
n20/D 1.347 (lit.)
bp
96-97 °C (lit.)
density
1.395 g/mL at 25 °C (lit.)
functional group
anhydride
chloro
ester
fluoro
SMILES string
FC(F)(Cl)C(=O)OC(=O)C(F)(F)Cl
InChI
1S/C4Cl2F4O3/c5-3(7,8)1(11)13-2(12)4(6,9)10
InChI key
VBJIFLOSOQGDRZ-UHFFFAOYSA-N
General description
Photolysis of the vapour of chlorodifluoroacetic anhydride has been studied over the range 19-201°C using 248nm radiation.
Application
Chlorodifluoroacetic anhydride has been used:
- for dual element acetylation tagging derivatization of amines by using microwave sustained helium emission detector
- as derivatization reagent in determination of estrone and 17β-estradiol in hair by GC-MS
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Skin Corr. 1B
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Photochemistry of anhydrides. Part 6.-Photolysis of chlorodifluoroacetic anhydride,(CF 2 ClCO) 2 O.
Watkins PE and Whittle E.
J. Chem. Soc., Faraday, 80(8), 2323-2329 (1984)
Multi-element taggant and dual homolog derivatization concepts in GC/MED.
Hagen DF, et al.
Spectrochimica Acta. Part B: Atomic Spectroscopy, 40(1), 335-347 (1985)
M H Choi et al.
The Analyst, 125(4), 711-714 (2000-07-13)
An efficient procedure is described for the determination of estrone and 17 beta-estradiol in hair by gas chromatography-mass spectrometry (GC-MS). The method involves alkyloxycarbonylation with isobutyl chloroformate (isoBCF) of phenolic hydroxy groups after alkaline digestion of hair samples. The resulting
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Association of cholinesterase with β-amyloid plaques and tau neurofibrillary tangles in Alzheimer's disease offers an opportunity to detect disease pathology during life. Achieving this requires development of radiolabelled cholinesterase ligands with high enzyme affinity. Various fluorinated acetophenone derivatives bind to
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