60765

Gel de silice

high-purity grade, with ~15% calcium sulfate and fluorescent indicator, GF₂₅₄, suitable for thin layer chromatography (TLC)

• Numéro CAS: 112926-00-8
• Numéro CE : 231-545-4
• Numéro MDL: MFCD00011232
• Code UNSPSC : 41115711
• ID de substance PubChem : 329759214
• Nomenclature NACRES : NC.07

Propriétés

• Qualité: high-purity grade; with ~15% calcium sulfate and fluorescent indicator
• Niveau de qualité: 100
• Forme: powder
• Fabricant/nom de marque: Sigma-Aldrich
• Technique(s): thin layer chromatography (TLC): suitable
• Superficie: 500 m²/g
• Taille des particules: <20 μm; >632 mesh
• Dimension de pores: 0.8 cm³/g pore volume; 60 Å pore size
• Point d'ébullition: 2230 °C
• Pf: >1600 °C
• Chaîne SMILES: O=[Si]=O
• InChI: 1S/O2Si/c1-3-2
• Clé InChI: VYPSYNLAJGMNEJ-UHFFFAOYSA-N

Description

Description générale

Silica gel is a rigid 3D network of colloidal silica. It is exclusively used as a support material for the active titanium(III) centers in Ziegler-Natta catalysts. Silica gel allows a controlled fragmentation resulting in the formation of uniform polymer particles with narrow particle size distribution and high bulk density. Silica gel is classified as below:
a. Aquagel - pores are filled with water
b. Xerogel - by the process of evaporation, aqueous phase in the pores are removed
c. Aerogel - solvent is removed by supercritical extraction

Application

• Chromatographic Separation: Silica gel is widely used as a stationary phase in chromatography for the separation of various chemical compounds. Innovations in silica gel modification, such as pentabromobenzyl group-modified silica gel, have enhanced the separation efficiency for metabolites like nicotinamide. This application is critical for pharmaceutical analysis and metabolomics studies, providing high precision and accuracy in the quantification of biologically relevant molecules (Ozaki et al., Analytical Biochemistry, 2022).


• Environmental Pollutant Detection: Silica gel is used to create molecularly imprinted polymers (MIPs) that selectively recognize and bind environmental pollutants. A notable application involves the embedding of quantum dots in molecularly imprinted silica gel to detect aminoimidazo-azaarenes (AIAs) in food samples. This method offers high selectivity and sensitivity, making it a powerful tool for food safety and environmental monitoring (Qiao et al., Current Analytical Chemistry, 2021).

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): nwg
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable
• Équipement de protection individuelle: Eyeshields, Gloves, type N95 (US)