925772

N,N′-Tetra(4-biphenyl)benzidine

≥97%

• Synonyme(s) : TBBDAz
• Formule empirique (notation de Hill): C₆₀H₄₄N₂
• Numéro CAS: 164724-35-0
• Poids moléculaire : 793.00
• Numéro MDL: MFCD11977303
• Code UNSPSC : 12352116
• Nomenclature NACRES : NA.21

Propriétés

• Description: PL: 425 nm (in DCM)
• Niveau de qualité: 100
• Pureté: ≥97%
• Forme: powder
• Couleur: white to light yellow
• Énergie orbitale: HOMO 5.3 eV ; LUMO 2.2 eV
• Absorption UV: λ: 357 nm A_max: in DCM
• InChI: 1S/C60H44N2/c1-5-13-45(14-6-1)49-21-33-55(34-22-49)61(56-35-23-50(24-36-56)46-15-7-2-8-16-46)59-41-29-53(30-42-59)54-31-43-60(44-32-54)62(57-37-25-51(26-38-57)47-17-9-3-10-18-47)58-39-27-52(28-40-58)48-19-11-4-12-20-48/h1-44H
• Clé InChI: WXAIEIRYBSKHDP-UHFFFAOYSA-N

Description

Application

Having N,N′-bis-(3-methylphenyl)-N,N′-bis-phenyl-benzidine (TPD) like unit, TBBDA (BPBPA) is electron-rich. As a result, it is used as a hole-transport material in organic light-emitting diodes (OLED).
Example of OLED Device Performance:
ITO/DNTPD (60 nm)/BPBPA (30 nm)/mCBP (10 nm)/mCBP:Ir(dbi)₃ (30 nm)/LG201 (35 nm)/
LiF (1 nm)/Al (200 nm)
Color: blue
EQE: Not known
Turn-On Voltage: 2.8V
Max. Luminance: ~ 9900 Cd/m²

Besides, for organic solar cell (OSCs) applications, its highest occupied molecular orbital energy value at 5.3 eV is well matched with a donor layer and its high mobility of 1.74 × 10^-2 cm²/Vs brings out an easy and rapid extraction of holes from the donor material.

N,N′-Tetra(4-biphenyl)benzidine can be used as an emissive layer or hole transporting material in studies such as organic light-emitting diodes (OLEDs), photovoltaics, organic field-effect transistors (OFETs).

Informations sur la sécurité

• Code de la classe de stockage: 11 - Combustible Solids
• Classe de danger pour l'eau (WGK): WGK 3