804150

SnAP 2,3-Bicyclo-(3,4-Pyr) M Reagent

• Synonyme(s) : (3R,4R)-tert-butyl 3-amino-4-((tributylstannyl)methoxy) pyrrolidine-1-carboxylate
• Formule empirique (notation de Hill): C₂₂H₄₆N₂O₃Sn
• Poids moléculaire : 505.32
• Code UNSPSC : 12352103
• ID de substance PubChem : 329768847
• Nomenclature NACRES : NA.22

Propriétés

• Forme: liquid
• Niveau de qualité: 100
• Densité: 1.180 at 25 °C
• Groupe fonctionnel: ether
• Température de stockage: −20°C
• Chaîne SMILES: CCCC[Sn](CCCC)(CO[C@H]1CN(C(OC(C)(C)C)=O)C[C@@H]1N)CCCC
• InChI: 1S/C10H19N2O3.3C4H9.Sn/c1-10(2,3)15-9(13)12-5-7(11)8(6-12)14-4;3*1-3-4-2;/h7-8H,4-6,11H2,1-3H3;3*1,3-4H2,2H3;/t7-,8-;;;;/m0..../s1
• Clé InChI: URTKNAYUDTUPJM-CFACWHMASA-N

Description

Application

SnAP Reagents provide a one-step route, in tandem with various aldehyde substrates, to saturated N-heterocycles. The synthesis of N-heterocycles through SnAP Reagents requires mild reaction conditions, and aldehydes bearing aryl, heteroaryl, glyoxyl, aliphatic, and halogenated groups are well tolerated. This product was introduced in collaboration with the Bode Research Group

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Autres remarques

Technology spotlight: SnAP Reagents
Professor product portal: Jeffrey Bode Research Group
SnAP Reagents for the Synthesis of Piperazines and Morpholines
SnAP reagents for the one-step synthesis of medium-ring saturated N-heterocycles from aldehydes
SnAP Reagents for a Cross-Coupling Approach to the One-Step Synthesis of Saturated N-Heterocycles
Bespoke SnAP Reagents for the Synthesis of C-Substituted Spirocyclic and Bicyclic Saturated N-Heterocycles

Informations sur la sécurité

• Pictogrammes: GHS06,GHS08,GHS09
• Mention d'avertissement: Danger
• Mentions de danger: H301,H312,H315,H319,H360FD,H372,H410
• Conseils de prudence: P202 - P273 - P280 - P301 + P310 - P302 + P352 + P312 - P305 + P351 + P338
• Classification des risques: Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1
• Code de la classe de stockage: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• Classe de danger pour l'eau (WGK): WGK 3
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable