Accéder au contenu
Merck
Toutes les photos(3)

Key Documents

View All Documentation

686859

Sigma-Aldrich

1,3,5-Tris(4-carboxyphenyl)benzene

greener alternative

≥98%, ≤20 wt. % solvent

Synonyme(s) :

4,4′,4′′,-Benzene-1,3,5-triyl-tris(benzoic acid)

Se connecterpour consulter vos tarifs contractuels et ceux de votre entreprise/organisme
Toutes les photos(3)

About This Item

Formule empirique (notation de Hill):
C27H18O6
Numéro CAS:
50446-44-1
Poids moléculaire :
438.43
Numéro MDL:
MFCD10000888
Code UNSPSC :
26111700
ID de substance PubChem :
329761077
Nomenclature NACRES :
NA.23

Niveau de qualité

100

Pureté

≥98%

Forme

solid

Caractéristiques du produit alternatif plus écologique

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Impuretés

≤20 wt. % solvent

Pf

322-327 °C

Autre catégorie plus écologique

Enabling,

Chaîne SMILES 

OC(=O)c1ccc(cc1)-c2cc(cc(c2)-c3ccc(cc3)C(O)=O)-c4ccc(cc4)C(O)=O

InChI

1S/C27H18O6/c28-25(29)19-7-1-16(2-8-19)22-13-23(17-3-9-20(10-4-17)26(30)31)15-24(14-22)18-5-11-21(12-6-18)27(32)33/h1-15H,(H,28,29)(H,30,31)(H,32,33)

Clé InChI

SATWKVZGMWCXOJ-UHFFFAOYSA-N

Description générale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

1,3,5-Tris(4-carboxyphenyl)benzene (H3BTB) is a star-shaped two-dimensional molecule that forms a self-assembled monolayer (SAM) on a variety of substrates. It can be used as a tritopic bridging ligand that facilitates the functionalization of polyoxometalate-based metal organic frameworks (MOFs) for potential usage in gas storage, gas separation, and catalysis.
1,3,5-Tris(4-carboxyphenyl)benzene (BTB) is a building block for Metal Organic Frameworks (MOFs). MOFs are 3D-microporous materials with potential applications in gas adsorption and separation technologies. BTB has been recently used as a linker to make MOFs with extremely high surface area such as MOF-177 (~ 5000 m2/g), a hydrogen absorbing material with an extremely high hydrogen storage capacity of 7.5% at 77K.

Pictogrammes

FlameExclamation markEnvironment
GHS02,GHS07,GHS09

Mention d'avertissement

Danger

Mentions de danger

H228,H315,H319,H410

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Sol. 1 - Skin Irrit. 2

Code de la classe de stockage

4.1B - Flammable solid hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

Faites votre choix parmi les versions les plus récentes :

Certificats d'analyse (COA)

Lot/Batch Number
SHBN1285
SHBG6824V
SHBC9184V
SHBB4003V
SHBB4003

Vous ne trouvez pas la bonne version ?

Si vous avez besoin d'une version particulière, vous pouvez rechercher un certificat spécifique par le numéro de lot.

Rechercher un(e) COA

Déjà en possession de ce produit ?

Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Les clients ont également consulté

Slide 1 of 1

1 of 1

2,5-Dihydroxyterephthalic acid 98%

Sigma-Aldrich

382132

2,5-Dihydroxyterephthalic acid

Two-dimensional 1, 3, 5-tris (4-carboxyphenyl) benzene self-assembly at the 1-phenyloctane/graphite interface revisited
Silly F
The Journal of Physical Chemistry C, 116(18), 10029-10032 (2012)
Chong Liu et al.
Faraday discussions, 201, 163-174 (2017-06-18)
Gradient MOFs contain directional gradients of either structure or functionality. We have successfully prepared two ternary gradient MOFs based on bMOF-100 analogues, namely bMOF-100/102/106 and bMOF-110/100/102, via cascade ligand exchange reactions. The cubic unit cell parameter discrepancy within an individual
The first tritopic bridging ligand 1, 3, 5-tris (4-carboxyphenyl)-benzene (H 3 BTB) functionalized porous polyoxometalate-based metal-organic framework (POMOF): from design, synthesis to electrocatalytic properties
Dong BX, et al.
Dalton Transactions, 44(3), 1435-1440 (2015)
Ram R R Prasad et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 24(57), 15309-15318 (2018-07-07)
Post-synthetic modification of the hafnium metal-organic framework MOF-808(Hf) to include triarylphosphine ligands is reported. Sulfonated phenylphosphines are incorporated without oxidation to give a "MOF ligand" that can complex late transition metals such as Ir and Rh to give a bifunctional
Meng-Yao Chao et al.
Dalton transactions (Cambridge, England : 2003), 47(38), 13722-13729 (2018-09-15)
The two-dimensional (2D) metal-organic framework (MOF) [Cd2.25Co0.75(BTB)2(DEF)4]·2(DEF)0.5 (1a, BTB = benzene-1,3,5-tribenzolate; DEF = N,N'-diethylformamide) featuring linear trimetallic cluster secondary building units (SBUs) and replaceable DEF solvates reacts smoothly with dipyridyl ligands DPS, DPDS, and BIPY (DPS = 4,4'-dipyridyl sulfide; DPDS
Afficher tous les articles scientifiques apparentés

Articles

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Metal-Organic Frameworks in Energy

Metal-organic frameworks offer high surface area materials for alternative energy applications through simple synthetic strategies.

Notre équipe de scientifiques dispose d'une expérience dans tous les secteurs de la recherche, notamment en sciences de la vie, science des matériaux, synthèse chimique, chromatographie, analyse et dans de nombreux autres domaines..

Contacter notre Service technique