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Sigma-Aldrich

Silver methanesulfonate

Synonyme(s) :

Silver methylsulfonate, Methanesulfonic acid silver salt

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About This Item

Formule linéaire :
AgSO3CH3
Numéro CAS:
2386-52-9
Poids moléculaire :
202.97
Numéro CE :
219-199-2
Numéro MDL:
MFCD00064795
Code UNSPSC :
12161600
ID de substance PubChem :
24879101
Nomenclature NACRES :
NA.22

Forme

solid

Niveau de qualité

100

Pertinence de la réaction

core: silver
reagent type: catalyst

Pf

252-256 °C (lit.)

Chaîne SMILES 

[Ag+].CS([O-])(=O)=O

InChI

1S/CH4O3S.Ag/c1-5(2,3)4;/h1H3,(H,2,3,4);/q;+1/p-1

Clé InChI

MLKQJVFHEUORBO-UHFFFAOYSA-M

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Catégories apparentées

Application

Gold Catalysts — 21st Century ′Gold Rush′
Catalyst for:
  • Heterocyclization reactions
  • CO2-mediated rearrangement of propargyl alcohols for the synthesis of a,ß-unsaturated ketones and esters

Pictogrammes

Exclamation mark
GHS07

Mention d'avertissement

Warning

Mentions de danger

H315,H319,H335

Classification des risques

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

dust mask type N95 (US), Eyeshields, Gloves

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Certificats d'analyse (COA)

Lot/Batch Number
MKCS7124
MKCR3717
MKCR8945
MKCQ5160
MKCM2372

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Consulter la Bibliothèque de documents

Claudio Pettinari et al.
Inorganic chemistry, 50(21), 11173-11183 (2011-10-18)
Five new silver(I) complexes of formulas [Ag(Tpms)] (1), [Ag(Tpms)(PPh(3))] (2), [Ag(Tpms)(PCy(3))] (3), [Ag(PTA)][BF(4)] (4), and [Ag(Tpms)(PTA)] (5) {Tpms = tris(pyrazol-1-yl)methanesulfonate, PPh(3) = triphenylphosphane, PCy(3) = tricyclohexylphosphane, PTA = 1,3,5-triaza-7-phosphaadamantane} have been synthesized and fully characterized by elemental analyses, (1)H, (13)C
Chad E Wujcik et al.
Journal of separation science, 33(6-7), 826-833 (2010-01-21)
Hydrophilic retention coefficients for 17 peptides were calculated based on retention coefficients previously published for TSKgel silica-60 and were compared with the experimental elution profile on a Waters Atlantis HILIC silica column using TFA and methanesulfonic acid (MSA) as ion-pairing
Eric D Nacsa et al.
Organic letters, 15(1), 38-41 (2012-12-15)
The cyclopropenone catalyzed nucleophilic substitution of alcohols by methanesulfonate ion with inversion of configuration is described. This work provides an alternative to the Mitsunobu reaction that avoids the use of azodicarboxylates and generation of hydrazine and phosphine oxide byproducts. This
Siddheshwar K Chauthe et al.
Bioorganic & medicinal chemistry letters, 22(6), 2251-2256 (2012-02-22)
A series of dimeric phloroglucinol compounds were synthesized in a single step using commercially available phloroglucinol and methanesulfonic acid. Based on the reported anticancer activity of plant derived dimeric phloroglucinols, these synthesized compounds were evaluated for their in vitro anti-proliferative
Tsung-Ming Shih et al.
Chemico-biological interactions, 187(1-3), 207-214 (2010-03-13)
This study compared the ability of nine oximes (HI-6, HLö7, MMB-4, TMB-4, carboxime, ICD585, ICD692, ICD3805, and 2-PAM) to reactivate in vivo cholinesterase (ChE) in blood, brain, and peripheral tissues in guinea pigs intoxicated by one of four organophosphorus nerve
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