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449903

Sigma-Aldrich

Lithium fluoride

greener alternative

≥99.99% trace metals basis

Synonyme(s) :

Fluorolithium

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About This Item

Formule linéaire :
LiF
Numéro CAS:
Poids moléculaire :
25.94
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.23

Qualité

anhydrous

Pureté

≥99.99% trace metals basis

Forme

powder and chunks

Caractéristiques du produit alternatif plus écologique

Design for Energy Efficiency
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sustainability

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Impuretés

≤100.0 ppm Trace Metal Analysis

Point d'ébullition

1673 °C/1 atm (lit.)

Pf

845 °C (lit.)

Solubilité

aqueous acid: slightly soluble(lit.)

Densité

2.64 g/mL at 25 °C (lit.)

Autre catégorie plus écologique

Chaîne SMILES 

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1

Clé InChI

PQXKHYXIUOZZFA-UHFFFAOYSA-M

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Description générale

Lithium fluoride is a white crystalline solid with a high melting point. It is widely applied in the field of rechargeable batteries, storage devices, and thermoluminescent materials. LiF is also used as a coupling layer in OLED or PLED devices to enhance electron injection. On the other hand, it is preferred for optical applications due to its wide band gap, which allows it to transmit light efficiently.
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Application

Lithium fluoride can be used:
  • As an additive to fabricate SiO@C/graphite composite anode materials for Li-ion batteries. LiF stabilizes solid electrolyte interphase (SEI) and enhances initial coulombic efficiency.
  • As a critical component in SEI for stabilizing the SEI layer and improving the cycling efficiency of Li metal batteries.
  • To fabricate electron contacts for high-efficiency n-type crystalline silicon solar cells.
  • To prepare solid-state light sources for radiation imaging detectors.
  • To synthesize highly crystalline MXene for asymmetric supercapacitor applications. And also, lightweight, flexible, and hydrophobic MXene foam with reasonable strength, high electrical conductivity, and an outstanding EMI-shielding performance.
  • As an electron-injection layer to fabricate ITO/PEDOT:PSS/perovskite/B3PYMPM/ LiF/Al OLED device with a quantum efficiency of 20%.

Pictogrammes

Skull and crossbones

Mention d'avertissement

Danger

Mentions de danger

Classification des risques

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Organes cibles

Respiratory system

Risques supp

Code de la classe de stockage

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Radiat. Prot. Dosim., 66, 101-101 (1996)
A safe etching route to synthesize highly crystalline Nb2CTx MXene for high performance asymmetric supercapacitor applications
Junpeng Xiao, et al.
Electrochimica Acta, 337, 135803-135803 (2020)
Improving the electrochemical properties of a SiO@C/graphite composite anode for high-energy lithium-ion batteries by adding lithium fluoride
Mao Xia, et al.
Applied Surface Science, 480, 410-418 (2019)
Photoluminescence of colour centres in lithium fluoride thin films: from solid-state miniaturised light sources to novel radiation imaging detectors
R M Montereali, et al.
Journal of Luminescence, 170, 761-769 (2016)
Lithium fluoride based electron contacts for high efficiency n-type crystalline silicon solar cells
James Bullock, et al
Advanced Energy Materials, 6, 1600241-1600241 (2016)

Articles

Professor Gogotsi and Dr. Shuck introduce MXenes: a promising family of two-dimensional materials with a unique combination of high conductivity, hydrophilicity, and extensive tunability.

Professor Gogotsi and Dr. Shuck introduce MXenes: a promising family of two-dimensional materials with a unique combination of high conductivity, hydrophilicity, and extensive tunability.

Professor Gogotsi and Dr. Shuck introduce MXenes: a promising family of two-dimensional materials with a unique combination of high conductivity, hydrophilicity, and extensive tunability.

Professor Gogotsi and Dr. Shuck introduce MXenes: a promising family of two-dimensional materials with a unique combination of high conductivity, hydrophilicity, and extensive tunability.

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