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224758

Sigma-Aldrich

Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate

powder

Synonyme(s) :

Ru(BPY)3, Ruthenium-tris(2,2′-bipyridyl) dichloride, Tris(2,2′-bipyridyl)ruthenium(II) chloride hexahydrate

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About This Item

Formule empirique (notation de Hill):
C30H24Cl2N6Ru · 6H2O
Numéro CAS:
50525-27-4
Poids moléculaire :
748.62
Numéro MDL:
MFCD00149670
Code UNSPSC :
12352103
ID de substance PubChem :
24853454
Nomenclature NACRES :
NA.23

Forme

powder

Niveau de qualité

100

Pertinence de la réaction

core: ruthenium
reagent type: catalyst

Capacité de réaction

reaction type: Photocatalysis

Pf

>300 °C (lit.)

Activation du photocatalyseur

450 nm

Chaîne SMILES 

[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Ru]Cl.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6

InChI

1S/3C10H8N2.2ClH.6H2O.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;;;;;;;;;/h3*1-8H;2*1H;6*1H2;/q;;;;;;;;;;;+2/p-2

Clé InChI

WHELTKFSBJNBMQ-UHFFFAOYSA-L

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Catégories apparentées

Description générale

Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate is a metal complex and is used as an luminescent dye. The metal complex in its ground state can be excited by visible light which leads to the formation of a spin-allowed excited state. This excited state undergoes radiationless deactivation very quickly to form spin-forbidden, long-lived luminescent excited state. It is used widely in electroluminescent devices.

Application

  • Used in the synthesis of hybrid catalysts which are used in oxidase based biosensors.
  • Used as a luminophore for multiplexed signalling in bio analysis.
  • Used in oxygen assesment in living cells.
Learn More at the Professor and Product Portal of Professor Teshik Yoon and Professor Corey Stephenson.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Produit(s) apparenté(s)

Réf. du produit
Description
Tarif

903426

Ru(p-CF3-bpy)3 (BF4)2, ≥95%

904767

[Ru(phen)3]Cl2, ≥95%

904945

[Ru(dmbpy)3](PF6)2, ≥95%

904953

[Ru(dtbbpy)3](PF6)2, ≥95%

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Gloves, type N95 (US)

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Certificats d'analyse (COA)

Lot/Batch Number
MKCV4811
MKCV8180
MKCT3761
MKCS6160
MKCT7773

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Attapulgite Clay Combined with Tris(2,2'bipyridyl)ruthenium(II) for the Enhancement of the
Electrogenerated Chemiluminescence Sensing
Gu B. et al
International Journal of Electrochemical Science, 7, 6202-6213 (2012)
A Theoretical and Experimental Framework for Understanding Electrogenerated Chemiluminescence (ECL) Emission at Bipolar Electrodes
Mavre F, et al
Analytical Chemistry, 81, 6218-6225 (2009)
Stéphanie Heux et al.
Applied and environmental microbiology, 77(19), 7040-7049 (2011-08-16)
Miniaturization and high-throughput screening are currently the focus of emerging research areas such as systems biology and systems biotechnology. A fluorescence-based screening assay for the online monitoring of oxygen and pH and a numerical method to mine the resulting online
Old Molecules, New Concepts:[Ru (bpy) 3] 2+ as a Molecular Encoder-Decoder
Ceroni, P., Bergamini, G., & Balzani, V.
Angewandte Chemie (International Edition in English), 121(45), 8668-8670 (2009)
Novel organic-inorganic hybrid material based on tris (2, 2'-bipyridyl) dichlororuthenium (II) hexahydrate and Dawson-type tungstophosphate K 7[H4PW18O62]? 18H2O as a bifuctional hydrogen peroxide electrocatalyst for biosensors
Ammam, M., & Easton, E. B.
Sensors and Actuators B, Chemical, 161(1), 520-527 (2012)
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Contenu apparenté

Stephenson Group – Professor Product Portal

Research in the Stephenson lab focuses upon the development of new chemical methods which enable the activation of chemical bonds under mild reaction conditions.

Yoon Group – Professor Product Portal

One major theme of research in the Yoon lab is the development of unique chemical transformations enabled by visible light photochemistry. A variety of transition metal photocatalysts responsive to visible light are known, and the Yoon lab has shown that their well understood photochemistry can be coupled to cycloadditions, arene oxidations, amine functionalizations, and thiol-ene reactions, among others.

Notre équipe de scientifiques dispose d'une expérience dans tous les secteurs de la recherche, notamment en sciences de la vie, science des matériaux, synthèse chimique, chromatographie, analyse et dans de nombreux autres domaines..

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