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120871

Sigma-Aldrich

Terephthaloyl chloride

≥99%, flakes

Synonyme(s) :

Terephthalic acid chloride, Terephthaloyl dichloride

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About This Item

Formule linéaire :
C6H4-1,4-(COCl)2
Numéro CAS:
100-20-9
Poids moléculaire :
203.02
Numéro Beilstein :
607796
Numéro CE :
202-829-5
Numéro MDL:
MFCD00000693
Code UNSPSC :
12352100
eCl@ss :
39050525
ID de substance PubChem :
24847435
Nomenclature NACRES :
NA.22

Densité de vapeur

7 (vs air)

Pression de vapeur

0.02 mmHg ( 25 °C)

Pureté

≥99%

Forme

flakes

Point d'ébullition

266 °C (lit.)

Pf

79-81 °C (lit.)

Solubilité

ethanol: soluble 100 mg/mL, clear, colorless

Groupe fonctionnel

acyl chloride

Chaîne SMILES 

ClC(=O)c1ccc(cc1)C(Cl)=O

InChI

1S/C8H4Cl2O2/c9-7(11)5-1-2-6(4-3-5)8(10)12/h1-4H

Clé InChI

LXEJRKJRKIFVNY-UHFFFAOYSA-N

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Catégories apparentées

Description générale

Terephthaloyl chloride is a highly reactive acid chloride derived from terephthalic acid. It is used as a cross-linking agent in polymer synthesis. Terephthaloyl chloride undergoes condensation reaction with difunctional α,ω-diaminopolystyrene to yield chain-extended polystyrene containing amide bonds along the polymer backbone. It undergoes interfacial reaction with bovine serum albumin to form thin cross-linked films.

Application

Terephthaloyl chloride was used in the synthesis of liquid crystalline thermosets by thermal cyclotrimerization of dicyanate compounds of ring substituted bis(4-hydroxyphenyl) terepthalates.

Informations légales

DuPont product

Pictogrammes

Skull and crossbonesCorrosion
GHS06,GHS05

Mention d'avertissement

Danger

Mentions de danger

H314,H331,H335

Classification des risques

Acute Tox. 3 Inhalation - Eye Dam. 1 - Skin Corr. 1A - STOT SE 3

Organes cibles

Respiratory system

Code de la classe de stockage

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de danger pour l'eau (WGK)

WGK 1

Point d'éclair (°F)

356.0 °F - closed cup

Point d'éclair (°C)

180 °C - closed cup

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificats d'analyse (COA)

Lot/Batch Number
SDBB0186
STBL4186
SDBB0343
STBL1682
STBG9848

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8.21029

Phthaloyl dichloride

Succinyl chloride 95%

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Succinyl chloride

p-Phenylenediamine sublimed, ≥99%

Sigma-Aldrich

695106

p-Phenylenediamine

N V Larionova et al.
International journal of pharmaceutics, 189(2), 171-178 (1999-10-28)
The objective of this study is to demonstrate the feasibility of microcapsules containing a protein and a proteinase inhibitor in order to allow the oral administration of proteic or peptidic drug. Starch/bovine serum albumin mixed-walled microcapsules were prepared using interfacial
Zeynep Ekemen et al.
Biomacromolecules, 12(12), 4291-4300 (2011-11-03)
In this work, we utilize a recently developed microbubbling process to generate controlled protein (bovine serum albumin, BSA) coated bubbles and then manipulate these to fabricate a variety of structures suitable for several generic biomedical applications, tissue engineering, and biosensor
M C Levy et al.
Journal of pharmaceutical sciences, 83(3), 419-422 (1994-03-01)
Microcapsules were prepared from human serum albumin (HSA) through interfacial cross-linking with terephthaloyl chloride (TC). Reaction times were increased from 2 to 60 min, while pH (9.8) and TC concentration (2.5% w/v) were kept constant. Fourier-transform infrared (FT-IR) spectra of
S Alexandridou et al.
Journal of microencapsulation, 18(6), 767-781 (2001-11-07)
Oil-containing polyterephthalamide microcapsules were synthesized by the interfacial polymerization of an oil-soluble monomer (terephthaloyl dichloride, TDC) and a mixture of two water-soluble monomers (diethylenetriamine, DETA, and 1, 6-hexamethylenediamine, HMDA). The influence of several synthesis parameters (e.g. concentration ratio of the
Yuushou Nakayama et al.
International journal of molecular sciences, 21(10) (2020-05-28)
Poly(ester amide)s are attracting attention because they potentially have excellent thermal and mechanical properties as well as biodegradability. In this study, we synthesized a series of novel poly(ester amide)s by introducing γ-aminobutyric acid (GABA) regularly into polyesters, and investigated their
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