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CRM52554

Supelco

Spiroxamine

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Synonym(s):

N-Ethyl-N-propyl-8-tert-butyl-1,4-dioxaspiro[4.5]dec-2-ylmethylamine

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About This Item

Empirical Formula (Hill Notation):
C18H35NO2
CAS Number:
118134-30-8
Molecular Weight:
297.48
MDL number:
MFCD03095708
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material
TraceCERT®

Quality Level

300

product line

TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

format

neat

storage temp.

2-8°C

SMILES string

CCCN(CC)CC1COC2(CCC(CC2)C(C)(C)C)O1

InChI

1S/C18H35NO2/c1-6-12-19(7-2)13-16-14-20-18(21-16)10-8-15(9-11-18)17(3,4)5/h15-16H,6-14H2,1-5H3

InChI key

PUYXTUJWRLOUCW-UHFFFAOYSA-N

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.comSpiroxamine is a systemic fungicide that belongs to the class of synthetic amines or morpholines. It targets the ∆14-reductase enzyme and inhibits sterol biosynthesis. It is used against powdery mildew, rust, and spot fungi on cereals and grapes for its protective, curative, and eradicative activities.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, spiroxamine is approved for use in the European Union (EU). A maximum residue limit (MRL) of 0.01 mg/kg and 0.05 mg/kg is applicable for the presence of spiroxamine in fresh/frozen fruits and tree nuts respectively, in accordance with Regulation (EC) No. 2016/452. Spiroxamine is to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The spiroxamine CRM may also find the following uses:

  • Development of an enantioselective method to determine three fungicide residues in grapevine, sugar beet, and wheat samples by gas chromatography-tandem mass spectrometry (GC-MS/MS)
  • Quantification of 19 neonicotinoids and fungicides from pollen and individual bumblebee samples using modified QuEChERS extraction with ultra-high performance liquid chromatography-tandem mass spectrometry (UHPLC-MS/MS)
  • Evaluation of a gas chromatographic method with electron capture and nitrogen phosphorus detection (GC/ECD/NPD) for the analysis of 46 pesticides in fresh peppermint samples
  • Multi-residue determination of 25 pesticide residues in red wine by gas chromatography-mass spectrometry(GC-MS)
  • QuEChERS extraction and liquid chromatography-tandem mass spectrometry based determination of 42 pesticides in six marijuana samples
  • Investigation of three different sample preparation methods to select the most suitable one for the analysis of 98 pesticides in globe artichoke leaves and fruit samples by LC-MS and GC-MS

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Signal Word

Warning

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2

Target Organs

Eyes

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

296.6 °F

Flash Point(C)

147 °C

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Certificates of Analysis (COA)

Lot/Batch Number
BCCF4268

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Ignaz J Buerge et al.
Journal of agricultural and food chemistry, 64(26), 5301-5309 (2016-06-02)
Metabolism of chiral pesticides in crops is typically studied using achiral analytical methods and, consequently, the stereoisomer composition of residues is unknown. In this study, we developed an enantioselective GC-MS/MS method to quantify residues of the fungicides fenpropidin, fenpropimorph, and
Andrea Kunova et al.
Microorganisms, 9(7), 1541-1541 (2021-08-08)
Grapevine powdery mildew is a principal fungal disease of grapevine worldwide. Even though it usually does not cause plant death directly, heavy infections can lead to extensive yield losses, and even low levels of the disease can negatively affect the
Arthur David et al.
Analytical and bioanalytical chemistry, 407(26), 8151-8162 (2015-09-04)
To accurately estimate exposure of bees to pesticides, analytical methods are needed to enable quantification of nanogram/gram (ng/g) levels of contaminants in small samples of pollen or the individual insects. A modified QuEChERS extraction method coupled with ultra-high-performance liquid chromatography
Validation of a QuEChERS-based gas chromatographic method for multiresidue pesticide analysis in fresh peppermint including studies of matrix effects
Slowik-Borowiec M
Food Analytical Methods, 8(6), 1413-1424 (2015)
Maja Pelajić et al.
Food chemistry, 200, 98-106 (2016-02-03)
A new multiresidue method was developed for determination of 25 pesticide residues in red wine by gas chromatography coupled to mass spectrometry with a single run of 23.63 min. Samples were extracted from wine with solid phase extraction using Oasis
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