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Sigma-Aldrich

Sodium selenite

anhydrous, ≥90.0% (RT)

Synonyme(s) :

Selenious acid disodium salt

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About This Item

Formule linéaire :
Na2SeO3
Numéro CAS:
Poids moléculaire :
172.94
Numéro CE :
Numéro MDL:
Code UNSPSC :
12352302
ID de substance PubChem :
Nomenclature NACRES :
NA.22

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Qualité

for analytical purposes

Niveau de qualité

Essai

≥90.0% (RT)

Forme

powder

Perte

≤0.5% loss on drying, 200 °C

Pf

>350 °C (lit.)

Chaîne SMILES 

[Na+].[Na+].[O-][Se]([O-])=O

InChI

1S/2Na.H2O3Se/c;;1-4(2)3/h;;(H2,1,2,3)/q2*+1;/p-2

Clé InChI

BVTBRVFYZUCAKH-UHFFFAOYSA-L

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Catégories apparentées

Application

Sodium selenite can be used:
  • In dehydrogenation of benzoins to benzils and, flavanones to flavones under thermal and microwave conditions.[1]
  • As a catalyst along with cysteine or glutathione in the reductive debromination of vic-dibromides to alkenes.[2]
  • To prepare bis(methylmercuric) selenide (BMS) by reacting with methylmercuric chloride and reduced glutathione or cysteine.[3]

Sodium selenite is a common source of selenium in the synthesis of zinc selenide (ZnSe).[4] It is used as a key precursor in the synthesis of bismuth selenide nanocomposites,[5] nickel cobalt selenides,[6] selenium nanobelts[7] and t-selenium nanotubes.[8]

Pictogrammes

Skull and crossbonesEnvironment

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

Risques supp

Code de la classe de stockage

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

Classe de danger pour l'eau (WGK)

WGK 2

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Certificats d'analyse (COA)

Lot/Batch Number

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Retrouvez la documentation relative aux produits que vous avez récemment achetés dans la Bibliothèque de documents.

Consulter la Bibliothèque de documents

Cellulose-directed growth of selenium nanobelts in solution.
Lu Q, et al.
Chemistry of Materials, 18(1) (2006)
Sodium selenite-dimethylsulfoxide: a highly efficient reagent for dehydrogenation
Lamba M and Makrandi JK
J. Chem. Res. (M), 2008(4), 225-226 (2008)
New method for bis (methylmercuric) selenide synthesis from methylmercuric chloride, sodium selenite and reduced glutathione
Naganuma A and Imura N
Chemosphere, 10(4), 441-443 (1981)
Bimetallic nickel cobalt selenides: a new kind of electroactive material for high-power energy storage.
Chen H, et al.
Journal of Material Chemistry A, 3(47), 23653-23659 (2015)
Multifunctional bismuth selenide nanocomposites for antitumor thermo-chemotherapy and imaging.
Li Z, et al.
ACS Nano, 10(1), 984-997 (2015)

Articles

Antioxidants protect biological systems from oxidative damage produced by oxygen-containing free radicals and from redoxactive transition metal ions such as iron, copper, and cadmium.

Questions

1–2 sur 2 questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 réponse
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 réponse
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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