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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
208671
Bis(triphenylphosphine)palladium(II) dichloride
98%
Synonyme(s) :
Dichlorobis(triphenylphosphine)palladium(II), Palladium(II)bis(triphenylphosphine) dichloride, PdCl2(PPh3)2
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About This Item
Produits recommandés
Niveau de qualité
Essai
98%
Forme
solid
Pertinence de la réaction
core: palladium
reagent type: catalyst
Capacité de réaction
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
Chaîne SMILES
Cl[Pd]Cl.c1(P(c2ccccc2)c3ccccc3)ccccc1.c4(P(c5ccccc5)c6ccccc6)ccccc4
InChI
1S/2C18H15P.2ClH.Pd/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;2*1H;/q;;;;+2/p-2
Clé InChI
YNHIGQDRGKUECZ-UHFFFAOYSA-L
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Description générale
Application
- Coupling of 2-iodoanisole and terminal alkynes to synthesize 2,3-disubstituted benzofurans.[2]
- Copper-free Sonogashira cross-coupling reaction to synthesize diphenylacetylene.[3]
- Regioselective hydrocarboxylation of styrene.[4]
- Negishi coupling of fluoroarylzinc pivalates to prepare fluorinated oligophenyls.[5]
- Coupling of iodo-α-β-unsaturated esters to afford tetrasubstituted olefins.[6]
Produit(s) apparenté(s)
Mention d'avertissement
Warning
Mentions de danger
Conseils de prudence
Classification des risques
Aquatic Chronic 4 - Skin Sens. 1A
Code de la classe de stockage
11 - Combustible Solids
Classe de danger pour l'eau (WGK)
WGK 3
Point d'éclair (°F)
Not applicable
Point d'éclair (°C)
Not applicable
Équipement de protection individuelle
Eyeshields, Gloves, type N95 (US)
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Les clients ont également consulté
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How is shipping temperature determined? And how is it related to the product storage temperature?
1 réponse-
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How can I determine the shelf life / expiration / retest date of this product?
1 réponse-
If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdfUtile ?
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What is Product 208671, Bis(triphenylphosphine)palladium(II) dichloride soluble in?
1 réponse-
It is soluble in chloroform, toluene, and benzene.
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Is Product 208671, Dichlorobis(triphenylphosphine)palladium(II), cis or trans?
1 réponse-
We have not specifically tested the material in regards to what isomer it is, however, based on the synthesis of it, it is believed to be predominately trans.
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What is the Department of Transportation shipping information for this product?
1 réponse-
Transportation information can be found in Section 14 of the product's (M)SDS.To access the shipping information for this material, use the link on the product detail page for the product.
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