Journal of the American Chemical Society, 137(21), 6790-6803 (2015-05-07)
We compare the singlet fission dynamics of five pentacene derivatives precipitated to form nanoparticles. Two nanoparticle types were distinguished by differences in their solid-state order and kinetics of triplet formation. Nanoparticles that comprise primarily weakly coupled chromophores lack the bulk
The Journal of chemical physics, 138(7), 074301-074301 (2013-03-01)
We present total, elastic, and inelastic cross sections for positron and electron scattering from tetrahydrofuran (THF) in the energy range between 1 and 5000 eV. Total cross sections (TCS), positronium formation cross sections, the summed inelastic integral cross sections (ICS)
Tetrahydrofuran-containing macrolides: a fascinating gift from the deep sea.
Chemistry (Weinheim an der Bergstrasse, Germany), 21(44), 15797-15805 (2015-09-17)
The reactivity of the all-ferrous FeN heterocubane [Fe4 (Ntrop)4 ] (1) with i) Brønsted acids, ii) σ-donors, iii) σ-donors/π-acceptors, and iv) one-electron oxidants has been investigated (trop = 5H-dibenzo[a,d]cyclo-hepten-5-yl). 1 showed self-re-assembling after reactions with i) and proved surprisingly inert in reactions with ii)
Advanced materials (Deerfield Beach, Fla.), 27(23), 3484-3491 (2015-05-06)
Polymer solar cells are fabricated with systematic variation of the phase purity. Photovoltaic tests demonstrate that devices with ca. 10% of mixed phases outperform pure-phase devices. Photophysical studies reveal the effects of mixed phase on charge generation and recombination. These
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