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Merck

CRM43234

Supelco

Mercaptodimethur

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

Sinónimos:

Mercaptodimethur

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About This Item

Fórmula empírica (notación de Hill):
C11H15NO2S
Número de CAS:
Peso molecular:
225.31
Beilstein:
1881431
Número MDL:
Código UNSPSC:
41116107
NACRES:
NA.24

grado

certified reference material
TraceCERT®

Nivel de calidad

Línea del producto

TraceCERT®

caducidad

limited shelf life, expiry date on the label

fabricante / nombre comercial

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

formato

neat

temp. de almacenamiento

2-30°C

cadena SMILES

CNC(=O)Oc1cc(C)c(SC)c(C)c1

InChI

1S/C11H15NO2S/c1-7-5-9(14-11(13)12-3)6-8(2)10(7)15-4/h5-6H,1-4H3,(H,12,13)

Clave InChI

YFBPRJGDJKVWAH-UHFFFAOYSA-N

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Descripción general

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Methiocarb is a synthetic carbamate pesticide that shows broad biological activity. It is widely used for its insecticidal and molluscicidal activity against snails, rice insects, and also on fruit crops for its bird-repelling nature.
As per the commission implementing regulation (EU) 2019/1606 of 27th September 2019, methiocarb (expressed as a sum of methiocarb, methiocarb sulfone, and methiocarb sulfoxide) is not approved for use in the European Union. A maximum residue limit (MRLs) of 0.01 to 0.1 mg/kg has been set for the presence of methiocarb in various products of plant and animal origin as per Reg (EU) 2021/155. Methiocarb is to be monitored in the Multiannual Control Programme for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.

Aplicación

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The methiocarb CRM may also find the following uses:

  • Determination of methiocarb in water sample using boron-doped diamond electrode (BDDE) and differential pulse voltammetry
  • Development of a method to simultaneously measure methiocarb and its metabolites in five food products of animal origin (milk, chicken, pork, beef, and eggs) by liquid chromatography-tandem mass spectrometry(LC-MS/MS)
  • Extraction and quantification of six carbamate pesticide residues in water, fruit, and vegetable samples using dispersive liquid-liquid microextraction and high-performance liquid chromatography
  • Simultaneous analysis of trace carbamate pesticide residues in tomato samples using graphene-based magnetic nanoparticles for their magnetic solid phase extraction and high-performance liquid chromatographic determination
  • Pre-concentration of 13 pesticide residues using a silica-based MSU-1 mesoporous material and their subsequent determination by UPLC-MS/MS in environmental water samples
  • Multi-residue determination of 200 pesticides and their metabolites in honeybee samples using liquid and gas chromatography coupled to tandem mass spectrometry

Productos recomendados

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Información legal

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictogramas

Skull and crossbonesEnvironment

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Código de clase de almacenamiento

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable


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Certificados de análisis (COA)

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Visite la Librería de documentos

L Kharbouche et al.
Talanta, 199, 612-619 (2019-04-07)
This paper describes the synthesis of a silica based MSU-1 mesoporous solid and its application as sorbent in solid-phase extraction to pre-concentrate thirteen pesticides of low-high polarity (methomyl, cymoxanil, carbofuran, monolinuron, isoproturon, methidathion, methiocarb, malathion, phosalone, diazinon, penconazole, neburon and
Na Li et al.
Talanta, 141, 212-219 (2015-05-13)
Graphene-based magnetic nanoparticles, comprising zero-valent iron, iron oxide-oxyhydroxide and graphene, were prepared through a simple one-step synthesis method, and subsequently applied to magnetic solid-phase extraction for the determination of trace carbamate pesticides in tomatoes coupled with high performance liquid chromatography.
Determination of carbamate insecticides in water, fruit, and vegetables by ultrasound-assisted dispersive liquid-liquid microextraction and high-performance liquid chromatography
Kongphonprom K and Burakham R
Analytical Letters, 49(6), 753-767 (2016)
Determination of methiocarb pesticide using differential pulse voltammetry with a boron-doped diamond electrode
Chylkova J, et al.
Analytical Methods : Advancing Methods and Applications, 7(11), 4671-4677 (2015)
Tomasz Kiljanek et al.
Journal of chromatography. A, 1435, 100-114 (2016-02-03)
A method for the determination of 200 pesticides and pesticide metabolites in honeybee samples has been developed and validated. Almost 98% of compounds included in this method are approved to use within European Union, as active substances of plant protection

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