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Merck

72240

Sigma-Aldrich

Aluminum-nickel alloy

purum, 50% Al basis, 50% Ni basis

Sinónimos:

Nickel-aluminum alloy, Raney®-Nickel alloy

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100 G
42,30 €
500 G
124,00 €

42,30 €


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100 G
42,30 €
500 G
124,00 €

About This Item

Número de CAS:
Número MDL:
Código UNSPSC:
12161600
ID de la sustancia en PubChem:
NACRES:
NA.22

42,30 €


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Nivel de calidad

grado

purum

Formulario

powder

composición

Al, 50%
Ni, 50%

idoneidad de la reacción

core: nickel
reagent type: catalyst

cadena SMILES

[Al].[Ni]

InChI

1S/Al.Ni

Clave InChI

NPXOKRUENSOPAO-UHFFFAOYSA-N

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Aplicación

Aluminum-nickel alloy can be used:
  • For the reduction of nitriles, nitro compounds and oximes to primary amines.[1]
  • For the conversion of carbonyl compounds to hydrocarbons.[2]
  • As a reducing agent to convert Ar-X derivatives to Ar-H compounds.[1]
  • For the synthesis of Raney nickel catalyst to be used as an alkylating agent.[3][4]
  • To synthesize non-pyrophoric Ni catalyst by alkali leaching.[5]
  • For the synthesis of alloyed skeletal Ni catalysts.[6]

Información legal

Raney is a registered trademark of W.R. Grace & Co.-Conn.

sustituido por

Referencia del producto
Descripción
Precios

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - Water-react 2

Código de clase de almacenamiento

4.3 - Hazardous materials which set free flammable gases upon contact with water

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Certificados de análisis (COA)

Lot/Batch Number

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Visite la Librería de documentos

Highly selective hydrogenation of C?C double bond in unsaturated carbonyl compounds over NiC catalyst.
Mahata N, et al.
Chemical Engineering Journal, 188(4), 155-159 (2012)
An environmentally benign and catalytically efficient non-pyrophoric Ni catalyst for aqueous-phase reforming of ethylene glycol.
Zhu LJ, et al.
Green Chemistry, 10(12), 1323-1330 (2008)
Reinvestigating Raney nickel mediated selective alkylation of amines with alcohols via hydrogen autotransfer methodology.
Mehta A, et al.
Applied Catalysis A: General, 478(4), 241-251 (2014)
Steam reforming of ethanol over skeletal Ni-based catalysts: A temperature programmed desorption and kinetic study
Zhang C, et al.
AIChE Journal, 60(2), 635-644 (2014)
Nickel-aluminum alloy as a reducing agent.
Keefer LK and Lunn G
Chemical Reviews, 89(3), 459-502 (1989)

Artículos

An article concerning self-propagating reactions induced by mechanical alloying, presented by Sigma-Aldrich.com.

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

Preguntas

1–2 de 2 Preguntas  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 respuesta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 respuesta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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