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Merck

45708

Zinc dimethyldithiocarbamate

PESTANAL®, analytical standard

Sinónimos:

Zinc dimethyldithiocarbamate, Dimethyldithiocarbamic acid zinc salt, Ziram

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Fórmula lineal:
(CH3)2NCSSZnSCSN(CH3)2
Número CAS:
Peso molecular:
305.82
UNSPSC Code:
41116107
NACRES:
NA.24
PubChem Substance ID:
EC Number:
205-288-3
Beilstein/REAXYS Number:
3707008
MDL number:

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InChI key

DUBNHZYBDBBJHD-UHFFFAOYSA-L

InChI

1S/2C3H7NS2.Zn/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2

SMILES string

CN(C)C(=S)S[Zn]SC(=S)N(C)C

grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

reaction suitability

reagent type: catalyst
core: zinc

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

Quality Level

mp

248-257 °C (lit.)

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

storage temp.

2-8°C

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1 of 4

Este artículo
457074568934326
Ziram PESTANAL®, analytical standard

Supelco

45708

Ziram

Zineb PESTANAL®, analytical standard

Supelco

45707

Zineb

Thiram PESTANAL®, analytical standard

Supelco

45689

Thiram

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

application(s)

agriculture
environmental

application(s)

agriculture
cleaning products
cosmetics
environmental
food and beverages
personal care

application(s)

agriculture
environmental

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

format

neat

format

neat

format

neat

format

neat

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

grade

analytical standard

grade

analytical standard

grade

analytical standard

grade

analytical standard

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

-

storage temp.

-

General description

Ziram is a fungicide, widely used for the protection of vegetable crops, seed foliage and fruits. It is also employed in rubber industry as an antioxidant and vulcanization accelerator.

Application

Ziram may be used as an analytical reference standard for the quantification of the analyte in environmental samples, grains, and vegetable samples using different analytical techniques.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3

target_organs

Liver,Blood, Respiratory system

Clase de almacenamiento

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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Spectrophotometric determination of ziram (dithiocarbamate fungicide) by thiocyanate and rhodamine 6G method
Mathew L, et al.
Talanta, 42(1), 41-43 (1995)
Determination of ziram in vegetable samples by square wave voltammetry
Qui P, et al.
Chinese Chemical Letters = Zhongguo Hua Xue Kuai Bao, 19(11), 1337-1340 (2008)
Zisis Vryzas et al.
Journal of agricultural and food chemistry, 50(8), 2220-2226 (2002-04-04)
A simple and rapid method is presented for the analysis of residues of ethylenebis(dithiocarbamate) (maneb, zineb, and mancozeb) and N,N-dimethyldithiocarbamate (thiram and ziram) fungicides in dry tobacco leaves and peaches. Residues are extracted and hydrolyzed to CS(2) in a single
Q Li et al.
International journal of immunopathology and pharmacology, 25(4), 883-891 (2013-01-10)
We previously found that ziram, a dithiocarbamate fungicide, significantly inhibited natural killer (NK) activity in a dose-dependent manner. To explore the mechanism of this inhibition, we investigated ziram-induced apoptosis in human NK cells. Human NK-92MI cells were treated with ziram
Thyneice R Taylor et al.
Cell biology and toxicology, 25(5), 447-455 (2008-08-02)
Human natural killer (NK) cells are central in immune defense against tumor and virally infected cells. Ziram is used as an accelerating agent in latex production and as an agricultural fungicide. Previous studies showed that continuous exposure to ziram inhibits

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