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Merck
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06856

Supelco

Duroquinone

Standard for quantitative NMR, TraceCERT®

Sinónimos:

2,3,5,6-Tetramethyl-1,4-benzoquinone, Tetramethyl-p-benzoquinone

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About This Item

Fórmula empírica (notación de Hill):
C10H12O2
Número de CAS:
527-17-3
Peso molecular:
164.20
Beilstein:
1909128
Número CE:
208-409-8
Número MDL:
MFCD00001604
Código UNSPSC:
41116107
ID de la sustancia en PubChem:
329748289
NACRES:
NA.24

grado

Standard for quantitative NMR
certified reference material
TraceCERT®

Nivel de calidad

300

descripción

qNMR Standard for organic solvents (2 ppm)

Línea del producto

TraceCERT®

caducidad

limited shelf life, expiry date on the label

condiciones de almacenamiento

under inert gas (Argon)

técnicas

gas chromatography (GC): suitable
qNMR: suitable

mp

110-112 °C (lit.)

aplicaciones

cleaning products
cosmetics
environmental
flavors and fragrances
food and beverages
personal care
pharmaceutical

Formato

neat

cadena SMILES

CC1=C(C)C(=O)C(C)=C(C)C1=O

InChI

1S/C10H12O2/c1-5-6(2)10(12)8(4)7(3)9(5)11/h1-4H3

Clave InChI

WAMKWBHYPYBEJY-UHFFFAOYSA-N

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Descripción general

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to SI unit kg and measured against primary material from an NMI, e.g. NIST.
Certified content incl. uncertainty and expiry date are given on the label. Information about trace impurities are stated on the certificate.
Download your certificate at: http://www.sigma-aldrich.com.

Check out our entire range of quantitative NMR standards (qNMR standards)

Otras notas

Chemcial Shift: 2 ppm (chemical shifts may slightly vary depending on the experimental conditions)
Suitable NMR solvents: CDCl3

Productos recomendados

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Información legal

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Código de clase de almacenamiento

13 - Non Combustible Solids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

Not applicable

Punto de inflamabilidad (°C)

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number

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J Maly et al.
Analytical and bioanalytical chemistry, 381(8), 1558-1567 (2005-04-12)
Mass transport of the bulk of the analyte to the electrode and through the bioactive layer can be significantly improved by use of the nanoelectrode array and defined arrangement of protein film. This phenomenon has been studied by (i) atomic-force
Xiao-Hui Duan et al.
The Journal of chemical physics, 120(21), 10025-10032 (2004-07-23)
Photoinduced electron transfer of the model system composed of vitamin E and duroquinone has been investigated using time-dependent density functional theory. Calculations for the excited states tell that the photoexcitation of the model system can directly yield the charge transfer
Said H Audi et al.
American journal of physiology. Lung cellular and molecular physiology, 289(5), L788-L797 (2005-07-05)
NAD(P)H:quinone oxidoreductase 1 (NQO1) plays a dominant role in the reduction of the quinone compound 2,3,5,6-tetramethyl-1,4-benzoquinone (duroquinone, DQ) to durohydroquinone (DQH2) on passage through the rat lung. Exposure of adult rats to 85% O2 for > or =7 days stimulates
Marilyn P Merker et al.
American journal of physiology. Lung cellular and molecular physiology, 290(3), L607-L619 (2005-10-26)
The objective of this study was to examine the impact of chronic hyperoxic exposure (95% O2 for 48 h) on intact bovine pulmonary arterial endothelial cell redox metabolism of 2,3,5,6-tetramethyl-1,4-benzoquinone (duroquinone, DQ). DQ or durohydroquinone (DQH2) was added to normoxic
R A Rothery et al.
Biochemistry, 40(17), 5260-5268 (2001-04-25)
We have investigated the functional relationship between three of the prosthetic groups of Escherichia coli nitrate reductase A (NarGHI): the two hemes of the membrane anchor subunit (NarI) and the [3Fe-4S] cluster of the electron-transfer subunit (NarH). In two site-directed
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