00375

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl

purum, ≥98.0% (HPLC)

• Fórmula empírica (notación de Hill): C₁₁H₂₁N₂O₂
• Número de CAS: 14691-89-5
• Peso molecular: 213.30
• Beilstein: 3546225
• Número CE: 423-840-3
• Número MDL: MFCD00043593
• Código UNSPSC: 12352005
• ID de la sustancia en PubChem: 329747053
• NACRES: NA.22

Propiedades

• grado: purum
• Nivel de calidad: 200
• Análisis: ≥98.0% (HPLC)
• puntuación de productos alternativos más sostenibles: old score: 9; new score: 8; Find out more about DOZN™ Scoring
• características de los productos alternativos más sostenibles: Waste Prevention; Safer Solvents and Auxiliaries; Inherently Safer Chemistry for Accident Prevention; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• mp: 143-145 °C (lit.); 143-146 °C
• categoría alternativa más sostenible: , Re-engineered
• temp. de almacenamiento: 2-8°C
• cadena SMILES: CC(=O)NC1CC(C)(C)N([O])C(C)(C)C1
• InChI: 1S/C11H21N2O2/c1-8(14)12-9-6-10(2,3)13(15)11(4,5)7-9/h9H,6-7H2,1-5H3,(H,12,14)
• Clave InChI: UXBLSWOMIHTQPH-UHFFFAOYSA-N

Descripción

Descripción general

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl undergoes one-electron oxidation and reduction reactions. Reaction products were analyzed by ¹H, ¹³C and ¹⁵N NMR spectral data.

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives . This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Waste Prevention”, “Safer Solvents and Auxiliaries” and “Inherently Safer Chemistry for Accident Prevention”. Click here to view its DOZN scorecard.

Aplicación

4-Acetamido-2,2,6,6-tetramethylpiperidine 1-oxyl radical may be employed in the catalytic system used for the regioselective oxidation of curdlan. It may be employed as model nitroxyl radical to study its reaction with thiophosgene. Reaction afforded 2,2,6,6-tetramethylpiperidine and 2,2,6,6-tetramethyl-1-hydroxypiperidine as major products.

Otras notas

New oxidant for the mild oxidation of alcohols to carbonyls

Información de seguridad

• Pictogramas: GHS07
• Palabra de señalización: Warning
• Frases de peligro: H302
• Consejos de prudencia: P264 - P270 - P301 + P312 - P501
• Clasificaciones de peligro: Acute Tox. 4 Oral
• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 1
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable
• Equipo de protección personal: dust mask type N95 (US), Eyeshields, Gloves