If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
F408
Ferrocene
98%
Sinónimos:
Bis(cyclopentadienyl)iron, Di(cyclopentadienyl)iron
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21,80 €
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About This Item
21,80 €
Productos recomendados
presión de vapor
0.03 mmHg ( 40 °C)
Nivel de calidad
Ensayo
98%
idoneidad de la reacción
core: iron
reagent type: catalyst
bp
249 °C (lit.)
mp
172-174 °C (lit.)
λmáx.
358 nm
temp. de almacenamiento
2-8°C
cadena SMILES
[Fe].[CH]1[CH][CH][CH][CH]1.[CH]2[CH][CH][CH][CH]2
InChI
1S/2C5H5.Fe/c2*1-2-4-5-3-1;/h2*1-5H;
Clave InChI
DFRHTHSZMBROSH-UHFFFAOYSA-N
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Aplicación
- As a scaffold for chiral ligands in asymmetric catalysis.[1]
- In ferrocene-based electrolytes for dye sensitized solar cells applications.[2]
- In the synthesis of unsymmetrical ferrocene ligands used as catalysts in cross-coupling, hydrogenation, allylic substitution, hydroformylation and aldol reactions.[3]
- In the synthesis of two-dimensional hexagonally ordered mesoporous carbon (CMK-5) via chemical vapor deposition method, which is used as a catalyst support in oxidation of methanol.[4]
- In the synthesis of molecular hybrids of ferrocene and fullerene (Bucky ferrocenes).[5]
- In the preparation of ferrocenium salt which is used as a mild oxidant.[6]
Palabra de señalización
Danger
Frases de peligro
Consejos de prudencia
Clasificaciones de peligro
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 1 - Flam. Sol. 1 - Repr. 1B - STOT RE 2 Inhalation
Órganos de actuación
Liver
Código de clase de almacenamiento
4.1B - Flammable solid hazardous materials
Clase de riesgo para el agua (WGK)
WGK 2
Punto de inflamabilidad (°F)
Not applicable
Punto de inflamabilidad (°C)
Not applicable
Equipo de protección personal
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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What is the thermal stability of the product ferrocene (F408) and what is the temperature limit for ferrocene before it decomposes into different elements or chemicals?
1 respuesta-
Decomposition temperature has not been tested for the product ferrocene (F408). Please refer to the following article for more information; J. Phys. Chem. B 2006, 110, 42, 20973–20977. Publication Date:September 29, 2006. https://doi.org/10.1021/jp0636571
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