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Merck

907642

Sigma-Aldrich

Cuprous thiocyanate

greener alternative

35 mg/mL in diethyl sulfide

Sinónimos:

Copper thiocyanate perovskite hole transport material, Copper(I) thiocyanate perovskite hole transport material, Thiocyanic acid in diethyl sulfide

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About This Item

Fórmula lineal:
CuSCN
Número MDL:
Código UNSPSC:
12352101
NACRES:
NA.23

formulario

liquid

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Design for Energy Efficiency
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sustainability

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Descripción general

We are committed to bringing you Greener Alternative Products,which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an enabling product used as a Hole Transport Material for high-performance solar cells and thus has been enhanced for energy efficiency. Click here for more information.

Aplicación

Layers of CuSCN exhibit high hole mobility, high thermal stability, and exceptional optical transparency across the UV-Vis/NIR spectrum. CuSCN finds application as an alternative to organic hole transport materials such as PEDOT:PSS and Spiro-MeOTAD in perovskite-based solar cells (PSCs). Photovoltaic conversion efficiencies of >20% have been reported in PSCs with CuSCN [5]. In addition, compared to Spiro-OMeTAD the CuSCN-based PSCs have been shown to exhibit better thermal stability.

Palabra de señalización

Danger

Frases de peligro

Clasificaciones de peligro

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 3

Punto de inflamabilidad (°F)

25.7 °F - closed cup

Punto de inflamabilidad (°C)

-3.5 °C - closed cup


Certificados de análisis (COA)

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Planar perovskite solar cells employing copper(I) thiocyanate/N,N′-di(1-naphthyl)-N,N′-diphenyl-(1,1′-biphenyl)-4,4′-diamine bilayer structure as hole transport layers
Tseng Z L ,et al.
Japanese Journal of Applied Physics, 57, 02CE07-02CE07 (2018)
High-Efficiency Organic Photovoltaic Cells Based on the Solution-Processable Hole Transporting Interlayer Copper Thiocyanate (CuSCN) as a Replacement for PEDOT:PSS
Gross N Y, et al.
Advanced Energy Materials, 5, 1401529-1401529 (2015)
Pichaya Pattanasattayavong et al.
Chemical communications (Cambridge, England), 49(39), 4154-4156 (2012-12-12)
The optical, structural and charge transport properties of solution-processed films of copper(I) thiocyanate (CuSCN) are investigated in this work. As-processed CuSCN films of ~20 nm in thickness are found to be nano-crystalline, highly transparent and exhibit intrinsic hole transporting characteristics
Perovskite solar cells with CuSCN hole extraction layers yield stabilized efficiencies greater than 20%
N Arora, et al.
Science, 358(6364), 768-771 (2017)
Pichaya Pattanasattayavong et al.
Advanced materials (Deerfield Beach, Fla.), 25(10), 1504-1509 (2013-01-03)
The wide bandgap and highly transparent inorganic compound copper(I) thiocyanate (CuSCN) is used for the first time to fabricate p-type thin-film transistors processed from solution at room temperature. By combining CuSCN with the high-k relaxor ferroelectric polymeric dielectric P(VDF-TrFE-CFE), we

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