900349

cataCXium A Pd G4

• Sinónimos: [di(adamantan-1-yl)(butyl)phosphine](methanesulfonato-κO)[2′-(methylamino)-2-biphenylyl]palladium
• Fórmula empírica (notación de Hill): C₃₈H₅₄NO₃PPdS
• Número de CAS: 2230788-67-5
• Peso molecular: 742.30
• Código UNSPSC: 12352103
• ID de la sustancia en PubChem: 329769810
• NACRES: NA.22

Propiedades

• Formulario: powder
• Nivel de calidad: 100
• Características: generation 4
• idoneidad de la reacción: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst; reaction type: Cross Couplings
• grupo funcional: phosphine
• cadena SMILES: CCCCP([C@@]12C[C@H]3C[C@@H](C1)C[C@@H](C2)C3)[C@@]4(C5)C[C@H]6C[C@H](C[C@@H]5C6)C4.CNC7=C(C8=CC=CC=C8[Pd]OS(C)(=O)=O)C=CC=C7
• InChI: 1S/C24H39P.C13H12N.CH4O3S.Pd/c1-2-3-4-25(23-11-17-5-18(12-23)7-19(6-17)13-23)24-14-20-8-21(15-24)10-22(9-20)16-24;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h17-22H,2-16H2,1H3;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1
• Clave InChI: ROZFJYIWIVSDBR-UHFFFAOYSA-M

Descripción

Aplicación

A fourth generation (G4) Buchwald precatalyst that is similar to the third generation (G3) precatalysts except that the amino group on the biphenyl backbone is methylated. This modification helps to prevent the limitations found when using the third generation precatalysts. It is air, moisture, and thermally-stable and shows good solubility in common organic solvents.

Información de seguridad

• Código de clase de almacenamiento: 11 - Combustible Solids
• Clase de riesgo para el agua (WGK): WGK 3