747904

Boxed reaction: Heck Reaction in Lipshutz Surfactant

• Código UNSPSC: 12161600

Propiedades

• idoneidad de la reacción: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• características de los productos alternativos más sostenibles: Waste Prevention; Designing Safer Chemicals; Design for Energy Efficiency; Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• categoría alternativa más sostenible: Aligned,
• temp. de almacenamiento: −20°C

Descripción

Descripción general

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Aplicación

This kit contains the reagents, catalyst, and solvent required to perform a Heck reaction in TPGS-750-M, a surfactant developed by the Lipshutz group as a greener alternative to organic solvents. This technology allows common metal-catalyzed reactions to be run under aqueous conditions, considerably reducing solvent waste. The components are pre-weighed in the appropriate amounts for a 1 mmol scale reaction.

Please refer to the attached Protocol for details.

Los componentes del kit también están disponibles por separado

• 676578 Bis(tri-tert-butylphosphine)palladium(0) 10 mg
• 763918 DL-α-Tocopherol methoxypolyethylene glycol succinate solution, 5 wt. % in H₂O 2 mL
• T0886 Triethylamine, ≥99% .42 mL

Información de seguridad

• Pictogramas: GHS02,GHS06,GHS05
• Palabra de señalización: Danger
• Frases de peligro: H225,H302,H311 + H331,H314,H335
• Consejos de prudencia: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Clasificaciones de peligro: Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - STOT SE 3
• Órganos de actuación: Respiratory system
• Código de clase de almacenamiento: 3 - Flammable liquids
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): 5.0 °F - closed cup
• Punto de inflamabilidad (°C): -15 °C - closed cup