325325
9-Methylcarbazole
99%
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About This Item
Fórmula empírica (notación de Hill):
C13H11N
Número de CAS:
Peso molecular:
181.23
Número CE:
Número MDL:
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
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Análisis
99%
mp
90-92 °C (lit.)
cadena SMILES
Cn1c2ccccc2c3ccccc13
InChI
1S/C13H11N/c1-14-12-8-4-2-6-10(12)11-7-3-5-9-13(11)14/h2-9H,1H3
Clave InChI
SDFLTYHTFPTIGX-UHFFFAOYSA-N
Descripción general
9-Methylcarbazole is a nitrogen-containing polycyclic aromatic hydrocarbon. Claisen-Schmidt condensation of 3-formyl-9-methylcarbazole with various amides of 3-aminoacetophenone yields N-{3-[3-(9-methyl-9H-carbazol-3-yl)-acryloyl]-phenyl}-benzamide/amide derivatives.
Aplicación
9-Methylcarbazole was used in facile synthesis of an organic electric conducting nanowire.
Palabra de señalización
Danger
Frases de peligro
Consejos de prudencia
Clasificaciones de peligro
Acute Tox. 4 Oral - Aquatic Acute 1 - Eye Dam. 1
Código de clase de almacenamiento
13 - Non Combustible Solids
Clase de riesgo para el agua (WGK)
WGK 3
Punto de inflamabilidad (°F)
Not applicable
Punto de inflamabilidad (°C)
Not applicable
Equipo de protección personal
Eyeshields, Gloves, type N95 (US)
Certificados de análisis (COA)
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W Yang et al.
Xenobiotica; the fate of foreign compounds in biological systems, 23(9), 973-982 (1993-09-01)
1. As previously reported (Yang and Davis 1992), N-methylcarbazole (NMC) is converted to N-hydroxymethylcarbazole (NHMC), and 3-hydroxy-N-hydroxymethylcarbazole (3-OH-NHMC), two relatively stable carbinolamine metabolites by the fungus Cunninghamella echinulata (ATCC 9244). Decomposition of these two carbinolamines yields the corresponding dealkylated metabolites
B O Ibe et al.
Experimental lung research, 20(3), 207-222 (1994-05-01)
N-methylcarbazole (NMC) is a procarcinogenic component of tobacco smoke particulate matter. It is metabolized by liver microsomes into some hydroxylated metabolites such as the potent mutagen N-hydroxymethylcarbazole (NHMC). Lung metabolism and toxicity of NMC is not known. Since the lung
G L Kedderis et al.
Molecular pharmacology, 23(3), 758-760 (1983-05-01)
The source of the oxygen atom in the product of the cytochrome P-450-catalyzed N-demethylation of N-methylcarbazole was determined by mass spectral analysis of the carbinolamine precursor of formaldehyde formed during incubation in oxygen 18-enriched medium. Initial experiments demonstrated that N-(hydroxymethyl)carbazole
W Yang et al.
Toxicology, 68(3), 217-226 (1991-01-01)
N-Methycarbazole (NMC), a carcinogen and mutagen in tobacco smoke, was converted to two major metabolites by primary cultured rat hepatocytes as measured by high performance liquid chromatography (HPLC): N-hydroxymethylcarbazole (NHMC) and carbazole. These two metabolites had comparable retention times and
W Yang et al.
Toxicology letters, 60(3), 307-314 (1992-05-01)
The formation of N-hydroxymethylcarbazole (NHMC), carbazole, 1-hydroxy-N-methylcarbazole, 2-hydroxy-N-methylcarbazole, and 3-hydroxy-N-methylcarbazole as products of mammalian liver microsomal metabolism of N-methylcarbazole (NMC) has been documented by several investigators. In previous studies in our laboratory, the fungus Cunninghamella echinulata (ATCC 9244) produced two
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