249491
Tris(4-chlorophenyl)phosphine
95%, powder
Sinónimos:
NSC 136459, Tris(p-chlorophenyl)phosphine
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| Talla/SKU | Disponibilidad | Precio |
|---|---|---|
1 g | Póngase en contacto con nuestro Servicio de Atención al Cliente para disponibilidad | 75,70 € 57,53 € |
Acerca de este artículo
57,53 €
Precio de catálogo75,70 €Ahorre 24 %Nombre del producto
Tris(4-chlorophenyl)phosphine, 95%
Quality Segment
assay
95%
form
powder
reaction suitability
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand
reaction type: Cross Couplings
mp
100-103 °C (lit.)
functional group
phosphine
SMILES string
Clc1ccc(cc1)P(c2ccc(Cl)cc2)c3ccc(Cl)cc3
InChI
1S/C18H12Cl3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
InChI key
IQKSLJOIKWOGIZ-UHFFFAOYSA-N
Application
- Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes
- Solvent-free Heck reactions
Cocatalyst in:
- Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents
- Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes
- Rhodium-catalyzed hydrogenation reactions
- Platinum-catalyzed allylation reactions
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Este artículo | |||
|---|---|---|---|
| description 95% | description 97% | description 97% | description 97% |
| assay 95% | assay 97% | assay 97% | assay 97% |
| reaction suitability reaction type: Negishi Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Heck Reaction, reagent type: ligand | reaction suitability reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Stille Coupling, reaction type: Sonogashira Coupling, reagent type: ligand, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Heck Reaction | reaction suitability reaction type: Suzuki-Miyaura Coupling, reaction type: Negishi Coupling, reagent type: ligand, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Stille Coupling, reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling, reaction type: Heck Reaction | reaction suitability reaction type: Stille Coupling, reagent type: ligand, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Suzuki-Miyaura Coupling, reaction type: Sonogashira Coupling, reaction type: Hiyama Coupling, reaction type: Heck Reaction, reaction type: Negishi Coupling |
| form powder | form solid | form liquid | form solid |
| functional group phosphine | functional group phosphine | functional group phosphine | functional group phosphine |
| Quality Level 100 | Quality Level 200 | Quality Level 100 | Quality Level 200 |
| mp 100-103 °C (lit.) | mp 108-110 °C (lit.) | mp - | mp 261-265 °C |
Palabra de advertencia
Warning
Códigos de peligro
Indicaciones de precaución
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Órganos diana
Respiratory system
Clase de almacenamiento
11 - Combustible Solids
¿Qué está pasando?
WGK 3
Punto de inflamación (°F)
Not applicable
Punto de inflamación (°C)
Not applicable
EPI (equipos de protección individual)
dust mask type N95 (US), Eyeshields, Gloves
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