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14520

Sigma-Aldrich

Tin(IV) chloride

fuming, ≥99%

Synonym(s):

Stannic chloride

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About This Item

Linear Formula:
SnCl4
CAS Number:
Molecular Weight:
260.52
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:

Quality Level

Assay

≥99%

reaction suitability

reagent type: catalyst
core: tin

density

2.217 g/mL at 20 °C (lit.)

anion traces

sulfate (SO42-): ≤100 mg/kg

cation traces

As: ≤50 mg/kg
Fe: ≤10 mg/kg

SMILES string

Cl[Sn](Cl)(Cl)Cl

InChI

1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4

InChI key

HPGGPRDJHPYFRM-UHFFFAOYSA-J

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Pictograms

CorrosionExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Yu-Jun Zhao et al.
Chemical communications (Cambridge, England), (12)(12), 1434-1436 (2008-03-14)
This communication describes a highly efficient intermolecular polyene cyclization method using steroidal acetals as the initiators to synthesize tetracyclic terpenoids; both good yields and good asymmetric induction were obtained.
Isabelle Bonhoure et al.
Environmental science & technology, 37(10), 2184-2191 (2003-06-06)
In this study, the immobilization mechanisms of Sn(IV) onto calcium silicate hydrates (C-S-H) and hardened cement paste (HCP) have been investigated by combining wet chemistry experiments with X-ray absorption spectroscopy (XAS). Evidence is presented which demonstrates the formation of a
Andreas T Messmer et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(47), 14989-14995 (2012-10-04)
Determining the structure of reactive intermediates is the key to understanding reaction mechanisms. To access these structures, a method combining structural sensitivity and high time resolution is required. Here ultrafast polarization-dependent two-dimensional infrared (P2D-IR) spectroscopy is shown to be an
Yu-Jun Zhao et al.
Journal of the American Chemical Society, 130(30), 10024-10029 (2008-07-09)
New strategies using chiral acetal or chiral mixed-acetal in the presence of Lewis acids (SnCl4 or TiCl4) to promote polyene cyclization reaction are described. Acetal-promoted and mixed-acetal-promoted polyene cyclization products are very versatile and can easily be converted into various
Jia Lu Xue et al.
Carbohydrate research, 344(13), 1646-1653 (2009-07-15)
Glycosidation of sugar peracetates (D-gluco, D-galacto) with SnCl(4) and CF(3)CO(2)Ag led to either 1,2-cis-, or 1,2-trans-glycosides, depending primarily on the alcohols used. In particular, 1,2-trans-glycosides, expected from acyl-protected glycosyl donors, were formed in high yields with alcohols sharing specific features

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