176109

Mercury(II) acetate

ACS reagent, ≥98.0%

• Sinónimos: Mercuric acetate
• Fórmula lineal: (CH₃COO)₂Hg
• Número de CAS: 1600-27-7
• Peso molecular: 318.68
• Beilstein: 3563831
• Número CE: 216-491-1
• Número MDL: MFCD00012165
• Código UNSPSC: 12352103
• ID de la sustancia en PubChem: 329751548
• NACRES: NB.24

Propiedades

• grado: ACS reagent
• Ensayo: ≥98.0%
• Formulario: powder
• idoneidad de la reacción: reagent type: catalyst; core: mercury
• impurezas: ≤0.01% insolubles
• residuo de reducción: ≤0.02%
• mp: 179-182 °C (lit.)
• trazas de anión: chloride (Cl^-): ≤0.005%; nitrate (NO₃^-): ≤0.005%; sulfate (SO₄^2-): ≤0.005%
• trazas de catión: Fe: ≤0.001%; Hg⁺: ≤0.4%; other heavy metals (as Pb): ≤0.002%
• cadena SMILES: CC(=O)O[Hg]OC(C)=O
• InChI: 1S/2C2H4O2.Hg/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
• Clave InChI: BRMYZIKAHFEUFJ-UHFFFAOYSA-L

Descripción

Descripción general

Mercury(II) acetate forms various addition compounds with olefins. Polarographic evaluation of these addition compounds has been proposed. It participates in the synthesis of nitrate esters, acetate esters, alcohols and ethers.

Mercury(II) acetate is a reagent mainly used in oxymercuration-demercuration reaction.

Aplicación

Due to its strong affinity towards sulfur, it finds application as a reagent in desulfurization reactions. Mercury(II) acetate may be used in the preparation of mercury(II) acetate-Nafion modified electrode, which can be used in anodic stripping voltammetry for the analysis of lead and copper ions in waste water samples.

Mercury(II) acetate may be used in the preparation of 2-benzylidene-3(2H)-benzofuran-3-ones (aurones). It may be used in the hydrothermal synthesis of [Hg₂(apca)₂]_n [apca = 3-aminopyrazine-2-carboxylate], a new mercury(I)-organic framework based on Hg₂^{2 +} dumbbell.

Información de seguridad

• Pictogramas: GHS06,GHS08,GHS09
• Palabra de señalización: Danger
• Frases de peligro: H300 + H310 + H330,H373,H410
• Consejos de prudencia: P262 - P264 - P273 - P280 - P302 + P352 + P310 - P304 + P340 + P310
• Clasificaciones de peligro: Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
• Código de clase de almacenamiento: 6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
• Clase de riesgo para el agua (WGK): WGK 3
• Punto de inflamabilidad (°F): Not applicable
• Punto de inflamabilidad (°C): Not applicable