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Merck
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Documentos

92732

Supelco

Trimethylsulfonium hydroxide solution

~0.25 M in methanol, for GC derivatization, LiChropur™

Sinónimos:

TMSH

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About This Item

Fórmula lineal:
(CH3)3S(OH)
Número de CAS:
17287-03-5
Peso molecular:
94.18
Beilstein/REAXYS Number:
3910286
MDL number:
MFCD00216756
UNSPSC Code:
12000000
PubChem Substance ID:
329770161
NACRES:
NA.22

grade

for GC derivatization

Quality Level

100

form

liquid

quality

LiChropur™

reaction suitability

reagent type: derivatization reagent
reaction type: Alkylations

packaging

pkg of 10 × 1 mL

concentration

~0.25 M in methanol

technique(s)

gas chromatography (GC): suitable

storage temp.

2-8°C

SMILES string

[OH-].C[S+](C)C

InChI

1S/C3H9S.H2O/c1-4(2)3;/h1-3H3;1H2/q+1;/p-1

InChI key

MDTPTXSNPBAUHX-UHFFFAOYSA-M

General description

Trimethylsulfonium hydroxide (TMSH) is a methylating reagent. It can be prepared by dissolving trimethylsulfonium iodide in methanol and water solvent further treating with silver oxide.

Application

TMSH solution has been used as a derivatizing agent in a study to determine the fatty acids in milk samples using thermochemolysis-gas chromatography-mass spectrometry.

Other Notes

Reagent for the methylation of nucleophiles, e.g. carboxylic acids, alcohols, thiols, N-heterocycles; Rapid derivatization of acids for GC by pre-column transesterification of glycerides

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 1

target_organs

Eyes,Central nervous system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

51.8 °F - closed cup

flash_point_c

11 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
BCCK2512
BCCG6745
BCCD6022
BCCB9475
BCBZ5264

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Félix B Rosumek et al.
Frontiers in zoology, 14, 36-36 (2017-07-19)
Trophic interactions are a fundamental aspect of ecosystem functioning, but often difficult to observe directly. Several indirect techniques, such as fatty acid analysis, were developed to assess these interactions. Fatty acid profiles may indicate dietary differences, while individual fatty acids
K.D. Muller et al.
Chromatographia, 30, 245-245 (1990)
W. Butte
Journal of Chromatography A, 261, 142-142 (1983)
Direct analysis of fatty acid profile from milk by thermochemolysis?gas chromatography?mass spectrometry.
Reis, Mariza Gomes, et al.
Journal of Chromatography A, 1218.2, 316-323 (2011)
Marco Beccaria et al.
Analytical and bioanalytical chemistry, 410(30), 7987-7996 (2018-10-30)
Gas chromatography (GC) coupled with electron ionization (EI) mass spectrometry (MS) is a well-established technique for the analysis of volatile and semi-volatile compounds. The main advantage is the highly repeatable fragmentation of the compounds into the ion source, generating intense
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