A88476

4-Methoxybenzoyl chloride

99%

• Sinónimos: 4-Anisoyl chloride, p-Anisoyl chloride
• Fórmula lineal: CH₃OC₆H₄COCl
• Número de CAS: 100-07-2
• Peso molecular: 170.59
• Beilstein: 471918
• Número CE: 202-816-4
• Número MDL: MFCD00000687
• Código UNSPSC: 12352100
• ID de la sustancia en PubChem: 24891375
• NACRES: NA.22

Propiedades

• Nivel de calidad: 200
• Ensayo: 99%
• Formulario: liquid
• índice de refracción: n20/D 1.581 (lit.)
• bp: 262-263 °C (lit.)
• mp: 22 °C (lit.)
• densidad: 1.260 g/mL at 20 °C (lit.)
• cadena SMILES: COc1ccc(cc1)C(Cl)=O
• InChI: 1S/C8H7ClO2/c1-11-7-4-2-6(3-5-7)8(9)10/h2-5H,1H3
• Clave InChI: MXMOTZIXVICDSD-UHFFFAOYSA-N

Descripción

Descripción general

4-Methoxybenzoyl chloride is one of the reactive acylating agents that can react with carboxylic acids, alcohols and amines to yield respective carboxylic anhydrides, esters and amides.

4-methoxybenzoyl chloride reacts with potassium thiocyanate to yield isothiocyanate derivative via nucleophilic addition-elimination mechanism.

Aplicación

• 4-Methoxybenzoyl chloride can be used as radical precursor in visible-light photocatalysis to synthesize various heterocyclic compounds.
• It can be used to synthesize acylphosphine ligands for the rhodium-catalyzed hydrosilylation of alkenes.
• Incorporation of 4-methoxybenzoyl chloride modified indium tin oxide (ITO) as cathode for the fabrication of organic light-emitting diodes (OLEDs) has been reported.
• 1,3 diketones synthesized from 4-methoxybenzoyl chloride can be used in one pot synthesis of various pyrazole derivatives.
• It can also be used in the total synthesis of bioactive compounds like echinoside A and salinosporamide A.

Información de seguridad

• Pictogramas: GHS05
• Palabra de señalización: Danger
• Frases de peligro: H314
• Consejos de prudencia: P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338 + P310
• Clasificaciones de peligro: Eye Dam. 1 - Skin Corr. 1B
• Riesgos supl.: EUH014
• Código de clase de almacenamiento: 8A - Combustible corrosive hazardous materials
• Clase de riesgo para el agua (WGK): WGK 1
• Punto de inflamabilidad (°F): 188.6 °F - closed cup
• Punto de inflamabilidad (°C): 87 °C - closed cup
• Equipo de protección personal: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter