422002

Hexamethylenediamine

technical grade, 70%

• Sinónimos: 1,6-Diaminohexane, 1,6-Hexanediamine, HMDA
• Fórmula lineal: NH₂(CH₂)₆NH₂
• Número de CAS: 124-09-4
• Peso molecular: 116.20
• Beilstein/REAXYS Number: 1098307
• MDL number: MFCD00008243
• UNSPSC Code: 12352100
• PubChem Substance ID: 24866408
• NACRES: NA.22

Propiedades

• grade: technical grade
• vapor density: 4 (vs air)
• assay: 70%
• form: liquid
• expl. lim.: 6.3 %
• technique(s): gas chromatography (GC): suitable
• refractive index: n20/D 1.439 (lit.)
• bp: 111-130 °C
• mp: 42-45 °C (lit.)
• solubility: alcohol: soluble(lit.); hydrocarbons: soluble(lit.); water: soluble(lit.)
• density: 0.89 g/mL at 25 °C (lit.)
• SMILES string: NCCCCCCN
• InChI: 1S/C6H16N2/c7-5-3-1-2-4-6-8/h1-8H2
• InChI key: NAQMVNRVTILPCV-UHFFFAOYSA-N
• Gene Information: rat ... Ppm1a(24666)

Descripción

General description

Hexamethylenediamine (1,6-Diaminohexane) is a linear aliphatic diamine. It reacts with various inorganic acids to afford mono and diacid salts. It can be prepared from adipic dinitrile via catalytic hydrogenation reaction.

Hexamethylenediamine is a useful industrial intermediate widely used in the production of aliphatic and semi-aromatic polyamides. Analysis of 1,6-hexamethylenediamine (HDA) in aqueous solution, human urine and plasma by capillary gas chromatographic method with thermionic specific detection has been reported.

Application

Hexamethylenediamine (1,6-hexanediamine, HDA ) may be used in the preparation of the following:

• polyamides and their hydrolytic and fungal degradability was investigated
• mullite ceramics
• dialkyl hexamethylene-1,6-dicarbamate (AHDC), via trans-esterification reaction of HDA and alkyl carbamates (AC) using FeCl₃ as catalyst

Other Notes

remainder water

Información de seguridad

• pictograms: GHS05,GHS07
• signalword: Danger
• hcodes: H302,H314,H335
• pcodes: P261 - P270 - P280 - P301 + P312 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 1
• flash_point_f: 201.2 °F
• flash_point_c: 94 °C