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185922

Sigma-Aldrich

Furan

≥99%

Sinónimos:

1,4-Epoxybuta-1,3-diene, Divinylene oxide, Oxacyclopentadiene, Oxole, Tetrole

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About This Item

Fórmula empírica (notación de Hill):
C4H4O
Número de CAS:
110-00-9
Peso molecular:
68.07
Beilstein/REAXYS Number:
103221
EC Number:
203-727-3
MDL number:
MFCD00003222
UNSPSC Code:
12352100
PubChem Substance ID:
24851189
NACRES:
NA.22

vapor density

2.35 (vs air)

Quality Level

100

vapor pressure

1672 mmHg ( 55 °C)
31.66 psi ( 55 °C)
493 mmHg ( 20 °C)
9.22 psi ( 20 °C)

assay

≥99%

form

liquid

contains

0.025 wt. % BHT as inhibitor

expl. lim.

14.3 %

refractive index

n20/D 1.421 (lit.)

bp

32 °C/758 mmHg (lit.)

solubility

alcohols: freely soluble
diethyl ether: freely soluble
water: insoluble

density

0.936 g/mL at 25 °C (lit.)

shipped in

wet ice

storage temp.

2-8°C

SMILES string

c1ccoc1

InChI

1S/C4H4O/c1-2-4-5-3-1/h1-4H

InChI key

YLQBMQCUIZJEEH-UHFFFAOYSA-N

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General description

Furan is a five membered heterocyclic compound that is highly volatile, flammable and a potential carcinogen. It undergoes Diels-Alder reaction with 2-bromoacrolein catalyzed by oxazaborolidine to yield chiral 7-oxabicyclo[2.2.1]heptene derivatives. Cationic bis(4-tert-butyloxazoline)Cu(II) complex catalyzed enantioselective Diels-Alder reaction between acryloyl oxazolidinone and furan to afford ent-shikimic acid has been described. Lewis acid catalyzed Diels-Alder reaction between furan and some dienophiles affords substituted cyclohexenols and cyclohexadienols.

Application

Furan was used in the following processes:
  • Preparation of the starting material required for the synthesis of calix[6]pyrrole.
  • To investigate the kinetics and mechanism of reactions of chlorine atoms with volatile organic compounds.
  • Catalytic transformation of furan to aromatics and olefins.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 1B - Flam. Liq. 1 - Muta. 2 - Skin Irrit. 2 - STOT RE 2

supp_hazards

EUH019

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

-32.8 °F - closed cup

flash_point_c

-36 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Catalytic enantioselective Diels-Alder addition to furan provides a direct synthetic route to many chiral natural products.
Corey EJ and Loh T-P.
Tetrahedron Letters, 34(25), 3979-3982 (1993)
Catalytic Conversion of Furan to Gasoline-Range Aliphatic Hydrocarbons via Ring Opening and Decarbonylation Reactions Catalyzed by Pt/γ-Al2O3.
Runnebaum RC, et al.
Catalysis Letters, 142(6), 664-666 (2012)
On the lewis acid catalyzed diels-alder reaction of furan. regio-and stereospecific synthesis of substituted cyclohexenols and cyclohexadienols.
Brion F.
Tetrahedron Letters, 23(50), 5299-5302 (1982)
Chemistry of furan conversion into aromatics and olefins over HZSM-5: a model biomass conversion reaction.
Cheng YT and Huber GW.
ACS Catalysis, 1(6), 611-628 (2011)
Samah R Khalil et al.
Ecotoxicology and environmental safety, 192, 110256-110256 (2020-02-06)
The modulatory role of the Spirulina platensis (SP) against furan-induced (FU) hepatic and renal damage was assessed in this study. For achieving this, sixty rats were distributed into six groups: control group, SP-administered group (300 mg/kg b.wt orally for 28 days)
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Diels–Alder Reaction

The Diels–Alder reaction is the reaction between a conjugated diene and an alkene (dienophile) to form unsaturated six-membered rings. It is also referred to as a cycloaddition.

Diels–Alder Reaction

The Diels–Alder reaction is the reaction between a conjugated diene and an alkene (dienophile) to form unsaturated six-membered rings. It is also referred to as a cycloaddition.

Diels–Alder Reaction

The Diels–Alder reaction is the reaction between a conjugated diene and an alkene (dienophile) to form unsaturated six-membered rings. It is also referred to as a cycloaddition.

Diels–Alder Reaction

The Diels–Alder reaction is the reaction between a conjugated diene and an alkene (dienophile) to form unsaturated six-membered rings. It is also referred to as a cycloaddition.

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