804398
[(TMEDA)Ni(o-tolyl)Cl]
95%
About This Item
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Niveau de qualité
Pureté
95%
Forme
powder
Pertinence de la réaction
core: nickel
reagent type: catalyst
Capacité de réaction
reaction type: Cross Couplings
Chaîne SMILES
CC1=CC=CC=C1[Ni]Cl.CN(C)CCN(C)C
InChI
1S/C7H7.C6H16N2.ClH.Ni/c1-7-5-3-2-4-6-7;1-7(2)5-6-8(3)4;;/h2-5H,1H3;5-6H2,1-4H3;1H;/q;;;+1/p-1
Clé InChI
NMLMESVZRUMFAE-UHFFFAOYSA-M
Catégories apparentées
Application
Produit(s) apparenté(s)
Code de la classe de stockage
11 - Combustible Solids
Classe de danger pour l'eau (WGK)
WGK 3
Point d'éclair (°F)
Not applicable
Point d'éclair (°C)
Not applicable
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Articles
Palladium catalysts in transition metal-catalyzed coupling reactions offer diversity, accessibility, and robustness over nickel catalysts.
Palladium catalysts in transition metal-catalyzed coupling reactions offer diversity, accessibility, and robustness over nickel catalysts.
Palladium catalysts in transition metal-catalyzed coupling reactions offer diversity, accessibility, and robustness over nickel catalysts.
Palladium catalysts in transition metal-catalyzed coupling reactions offer diversity, accessibility, and robustness over nickel catalysts.
Contenu apparenté
Research in the Doyle group focuses on two areas: nucleophilic fluorination and nickel catalysis. The Doyle group has developed several reagents that advance these research areas. In fluorination, 2-pyridinesulfonyl fluoride (PyFluor) can be used for the mild deoxyfluorination of primary and secondary alcohols, a procedure which is normally accomplished by the sensitive reagent DAST. In nickel catalysis, the Doyle group has developed a modular, air-stable nickel precatalyst, [(TMEDA)Ni(o-tolyl)Cl], which has broad utility for a wide variety of reactions. This precatalyst can be used in place of Ni(cod)2, NiCl2, as well as other reported precatalysts. Doyle has also reported electron-deficient olefin ligands as a new class of ligand for accelerated reductive elimination. In particular, the sultam-derived ligand Fro-DO has been found to be critical for high yields in the cross-coupling of tertiary aziridines to form quaternary centers.
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