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Sigma-Aldrich

Nickel(II) acetylacetonate

95%

Synonyme(s) :

2,4-Pentanedione nickel(II) derivative, Ni(acac)2

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About This Item

Formule linéaire :
Ni(C5H7O2)2
Numéro CAS:
3264-82-2
Poids moléculaire :
256.91
Numéro Beilstein :
4157970
Numéro CE :
221-875-7
Numéro MDL:
MFCD00000024
Code UNSPSC :
12352103
ID de substance PubChem :
24857123
Nomenclature NACRES :
NA.23

Niveau de qualité

100

Pureté

95%

Forme

solid

Pertinence de la réaction

core: nickel
reagent type: catalyst

Pf

230 °C (dec.) (lit.)

Chaîne SMILES 

CC(=O)\C=C(\C)O[Ni]O\C(C)=C/C(C)=O

InChI

1S/2C5H8O2.Ni/c2*1-4(6)3-5(2)7;/h2*3,6H,1-2H3;/q;;+2/p-2/b2*4-3-;

Clé InChI

BMGNSKKZFQMGDH-FDGPNNRMSA-L

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Description générale

Nickel(II) acetylacetonate, known as bis(acetylacetonato)nickel(II) or Ni(acac)2, is a blue-green crystalline compound soluble in water. It finds application in catalysis, materials synthesis, and organic chemistry, playing a crucial role as a catalyst in various reactions and serving as an important precursor for the development of nickel-based nanomaterials and catalysts used in industrial processes and organic transformations.

Application

Nickel(II) acetylacetonate can be:   
  • Used as a precursor to synthesize Ni-based nanomaterials such as NiO/C nanocomposite and crystalline NiO nanoparticles via different synthetic methods like non-isothermal decomposition and solvothermal method.,·      
  • Used to prepare Ni catalysts such as Nickel(II) complexes, and hierarchical Ni/beta catalysts for various organictransformations.
  • Nickel(II) acetylacetonate has several applications in catalysis: It is used as a catalyst for the polymerization of olefins and transesterification reactions.    
  • Nickel(II) acetylacetonate can be employed as a catalyst to promote Michael additions.

Produit(s) apparenté(s)

Réf. du produit
Description
Tarif

912794

Ni(COD)(DQ), ≥95%

Pictogrammes

Health hazardExclamation mark
GHS08,GHS07

Mention d'avertissement

Danger

Classification des risques

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Carc. 1A - Muta. 2 - Resp. Sens. 1 - Skin Sens. 1

Code de la classe de stockage

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

428.0 °F

Point d'éclair (°C)

220 °C

Équipement de protection individuelle

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Certificats d'analyse (COA)

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Yueping Zhao et al.
Small (Weinheim an der Bergstrasse, Germany), 15(17), e1900288-e1900288 (2019-03-29)
The catalytic performance of Pt-based catalysts for oxygen reduction reactions (ORR) can generally be enhanced by constructing high-index exposed facets (HIFs). However, the synthesis of Pt alloyed high-index skins on 1D non-Pt surfaces to further improve Pt utilization and stability
Huiming Li et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 24(45), 11748-11754 (2018-06-06)
The phase of nanocrystals has a key role in the modulation of catalytic properties. Uniform and well-crystallized nickel phosphide nanocrystals with controlled phases (Ni5 P4 , Ni2 P, and Ni12 P5 ) and narrow size distributions are synthesized by a
Lin Chen et al.
Nature communications, 8, 14136-14136 (2017-01-11)
Incorporating oxophilic metals into noble metal-based catalysts represents an emerging strategy to improve the catalytic performance of electrocatalysts in fuel cells. However, effects of the distance between the noble metal and oxophilic metal active sites on the catalytic performance have
Bowen Yu et al.
Nanotechnology, 25(32), 325602-325602 (2014-07-24)
Ni-assisted thermal chemical vapor deposition (TCVD) is one of the most common techniques for the growth of carbon nanofibres/nanotubes (CNFs/CNTs). However, some fundamental issues related to the catalytic growth of CNFs/CNTs, such as the low-limit growth temperature, the limiting steps
Husileng Lee et al.
ChemSusChem, 13(12), 3277-3282 (2020-04-02)
Water oxidation is the bottleneck reaction in artificial photosynthesis. Exploring highly active and stable molecular water oxidation catalysts (WOCs) is still a great challenge. In this study, a water-soluble NiII complex bearing a redox non-innocent tetraamido macrocyclic ligand (TAML) is
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