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672661

Sigma-Aldrich

1-Phenyl-2-(di-tert.-butyl-phosphino)-1H-pyrrole

95%

Synonyme(s) :

cataCXium® PtB

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About This Item

Formule empirique (notation de Hill):
C18H26NP
Numéro CAS:
Poids moléculaire :
287.38
Numéro Beilstein :
9626114
Numéro MDL:
Code UNSPSC :
12352005
ID de substance PubChem :
Nomenclature NACRES :
NA.22

Niveau de qualité

Pureté

95%

Capacité de réaction

reaction type: Asymmetric synthesis

Pertinence de la réaction

reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction

reagent type: ligand
reaction type: Dehydrogenation

reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

Groupe fonctionnel

phosphine

Chaîne SMILES 

CC(C)(C)P(c1cccn1-c2ccccc2)C(C)(C)C

InChI

1S/C18H26NP/c1-17(2,3)20(18(4,5)6)16-13-10-14-19(16)15-11-8-7-9-12-15/h7-14H,1-6H3

Clé InChI

DVVDGSKDQGMLPW-UHFFFAOYSA-N

Description générale

sold in collaboration with Solvias AG

Informations légales

WO 2004/101581
cataCXium is a registered trademark of Umicore AG & Co. KG

Code de la classe de stockage

11 - Combustible Solids

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

Équipement de protection individuelle

Eyeshields, Gloves, type N95 (US)


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Michelle Muñoz-Osses et al.
Dalton transactions (Cambridge, England : 2003), 47(39), 13861-13869 (2018-09-19)
Cyrhetrenyl aldehyde derivatives [(η5-C5H4CHO)Re(CO)2PR3] with R = methyl (Me, 2a), phenyl (Ph, 2b), and cyclohexyl (Cy, 2c) were synthesized by a photochemical reaction from the starting material [(η5-C5H4CHO)Re(CO)3] (1) and the corresponding phosphines. The complexes were fully characterized by FT-IR
Hai T Dong et al.
Inorganic chemistry, 59(20), 14967-14982 (2020-09-30)
We previously reported the synthesis and preliminary characterization of a unique series of low-spin (ls) {FeNO}8-10 complexes supported by an ambiphilic trisphosphineborane ligand, [Fe(TPB)(NO)]+/0/-. Herein, we use advanced spectroscopic techniques and density functional theory (DFT) calculations to extract detailed information
Cen Tang et al.
ACS nano, 14(9), 11605-11612 (2020-09-01)
The capping reagent plays an essential role in the functional properties of gold nanoparticles (AuNPs). Multiple stimuli-responsive materials are generated via diverse surface modification. The ability of the organic ligand shell on a gold surface to create a porous shell
Xi Kang et al.
Chemical Society reviews, 49(17), 6443-6514 (2020-08-08)
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles, providing unique opportunities for investigating the quantum effects and precise structure-property correlations at the atomic level. As a versatile strategy, alloying can largely improve the physicochemical performances compared to
Xun Pan et al.
Dalton transactions (Cambridge, England : 2003), 49(42), 14941-14950 (2020-10-21)
The synthesis of four heteroleptic dinuclear Cu(i) complexes bearing tetraphosphine and diimine ligands was reported. Complexes 1-3 were successfully obtained through microwave synthesis while complex 4 was synthesized through traditionally stirring at room temperature. These complexes are listed as follows:

Articles

cataCXium® ligands facilitate cross-coupling reactions, essential in polymer science, fine chemicals, and pharmaceutical industries.

cataCXium® ligands facilitate cross-coupling reactions, essential in polymer science, fine chemicals, and pharmaceutical industries.

cataCXium® ligands facilitate cross-coupling reactions, essential in polymer science, fine chemicals, and pharmaceutical industries.

cataCXium® ligands facilitate cross-coupling reactions, essential in polymer science, fine chemicals, and pharmaceutical industries.

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