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Sigma-Aldrich

Palladium(II) chloride solution

5 wt. % in 10 wt. % HCl

Synonyme(s) :

Dichloropalladium, Palladium dichloride, Palladous chloride

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About This Item

Formule linéaire :
PdCl2
Numéro CAS:
7647-10-1
Poids moléculaire :
177.33
Numéro MDL:
MFCD00003558
Code UNSPSC :
12161600
ID de substance PubChem :
24857119
Nomenclature NACRES :
NA.22

Forme

liquid

Niveau de qualité

100

Pertinence de la réaction

core: palladium
reagent type: catalyst

Capacité de réaction

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling

Concentration

5 wt. % in 10 wt. % HCl

Densité

1.06 g/mL at 25 °C

Chaîne SMILES 

Cl[Pd]Cl

InChI

1S/2ClH.Pd/h2*1H;/q;;+2/p-2

Clé InChI

PIBWKRNGBLPSSY-UHFFFAOYSA-L

Catégories apparentées

Description générale

Palladium(II) chloride is a representative salt of Pd(II) that is used as a precursor to prepare palladium catalysts for various reactions, such as Heck coupling, Suzuki coupling, Sonagashira coupling, and Buchwald-Hartwig coupling. It is also used as an oxidizing agent.

Application

Used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.

Pictogrammes

CorrosionExclamation markEnvironment
GHS05,GHS07,GHS09

Mention d'avertissement

Danger

Mentions de danger

H290,H317,H318,H410

Classification des risques

Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Skin Sens. 1

Code de la classe de stockage

8B - Non-combustible corrosive hazardous materials

Classe de danger pour l'eau (WGK)

WGK 3

Point d'éclair (°F)

Not applicable

Point d'éclair (°C)

Not applicable

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Mathis, M. et al.
Chemistry of Materials, 10, 3568-3568 (1998)
Gábor Kovács et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(18), 5612-5619 (2012-03-31)
First-principles molecular dynamics coupled with metadynamics have been used to gain a deeper insight into the reaction mechanism of the Wacker process by determining the nature of the active species. An explicit and dynamic representation of the aqueous solvent, which
Buyi Li et al.
Advanced materials (Deerfield Beach, Fla.), 24(25), 3390-3395 (2012-06-08)
Highly dispersed palladium chloride catalysts locked in triphenylphosphine-functionalized knitting aryl network polymers (KAPs) are developed and exhibit excellent activity under mild conditions in the Suzuki-Miyaura cross-coupling reactions of aryl chlorides in aqueous media. This work highlights that the microporous polymers
Maozhong Miao et al.
Organic letters, 14(11), 2718-2721 (2012-05-16)
A novel PdCl(2)-catalyzed oxidative cycloisomerization of 3-cyclopropylideneprop-2-en-1-ones, providing a facile synthesis of highly strained functionalized 2-alkylidenecyclobutanones via furan-fused cyclobutene intermediates, is reported. An interesting route to 2(3H)-furanones with a spiro-cyclopropane unit from the obtained 2-alkylidenecyclobutanones via a ring-contraction rearrangement reaction
Juraj Velcicky et al.
Journal of the American Chemical Society, 133(18), 6948-6951 (2011-04-21)
A one-pot protocol for the cyanomethylation of aryl halides through a palladium-catalyzed reaction with isoxazole-4-boronic acid pinacol ester was developed. Mechanistically, the reaction proceeds through (1) Suzuki coupling, (2) base-induced fragmentation, and (3) deformylation as shown by characterization of all
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