If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
280909
(Chloromethylene)dimethyliminium chloride
95%
Synonyme(s) :
(Chlormethylene)dimethylammonium chloride, Arnold′s reagent, Dimethylchloroformiminium chloride, Vilsmeier reagent
About This Item
Produits recommandés
Essai
95%
Forme
solid
Capacité de réaction
reaction type: C-C Bond Formation
Impuretés
<5% DMF
Pf
132 °C (dec.) (lit.)
Groupe fonctionnel
amine
chloro
Température de stockage
2-8°C
Chaîne SMILES
[Cl-].C\[N+](C)=C\Cl
InChI
1S/C3H7ClN.ClH/c1-5(2)3-4;/h3H,1-2H3;1H/q+1;/p-1
Clé InChI
QQVDYSUDFZZPSU-UHFFFAOYSA-M
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Application
- β-Lactams vis the Staudinger reaction
- N-vinyl substituted indoles via cross coupling of NH-indoles with vinyl bromides
- Multi ring-fused 2-pyridone-based fluorescent scaffold
- ester prodrugs as anti-poxvirus agents
- Trimethine cyanine dyes for sensing G-quadruplex formation
- Phospha-isosteres via Hundsdiecker-Barton iododecacarboxylation
- 2-Azetidinones via [2+2]-cycloaddition
Used for studying organic photosensitizers for application in dye-sensitized solar cells
Mention d'avertissement
Danger
Mentions de danger
Classification des risques
Acute Tox. 4 Oral - Eye Dam. 1 - Repr. 1B - Skin Corr. 1A
Risques supp
Code de la classe de stockage
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
Classe de danger pour l'eau (WGK)
WGK 3
Point d'éclair (°F)
Not applicable
Point d'éclair (°C)
Not applicable
Équipement de protection individuelle
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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