156671

Potassium tert-butoxide

reagent grade, ≥98%

• Synonyme(s) : Potassium T-butoxide
• Formule linéaire : (CH₃)₃COK
• Numéro CAS: 865-47-4
• Poids moléculaire : 112.21
• Beilstein: 3556712
• Numéro CE : 212-740-3
• Numéro MDL: MFCD00012162
• Code UNSPSC : 12352303
• ID de substance PubChem : 24849626
• Nomenclature NACRES : NA.22

Propriétés

• Qualité: reagent grade
• Niveau de qualité: 200
• Pression de vapeur: 1 mmHg ( 220 °C)
• Essai: ≥98%
• Forme: solid
• Caractéristiques du produit alternatif plus écologique: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• Pf: 256-258 °C (dec.) (lit.)
• Autre catégorie plus écologique: Aligned,
• Chaîne SMILES: [K+].CC(C)(C)[O-]
• InChI: 1S/C4H9O.K/c1-4(2,3)5;/h1-3H3;/q-1;+1
• Clé InChI: LPNYRYFBWFDTMA-UHFFFAOYSA-N

Description

Description générale

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

Potassium tert-butoxide has been used as a strong base in the enantioselective synthesis of amines by transfer hydrogenation of N-(tertbutylsulfinyl)imines.
It can also be used:

• To synthesize aliphatic and aromatic amides from corresponding esters and amines.
• As a base in the intramolecular cyclization of aryl ethers, amines, and amides.
• As a catalyst to prepare styrene derivatives from aryl halides and alkenes by Mizoroki-Heck reaction.

Used for greener amidation of esters.

tert-Butoxide-Assisted Amidation of Esters under Green Conditions

Potassium tert-butoxide may be used as a base in the intramolecular cyclization of iodo arene to afford benzopyran via microwave method of synthesis.

Informations sur la sécurité

• Pictogrammes: GHS02,GHS05
• Mention d'avertissement: Danger
• Mentions de danger: H228,H252,H314
• Conseils de prudence: P210 - P235 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Classification des risques: Eye Dam. 1 - Flam. Sol. 1 - Self-heat. 2 - Skin Corr. 1A
• Risques supp: EUH014
• Code de la classe de stockage: 4.2 - Pyrophoric and self-heating hazardous materials
• Classe de danger pour l'eau (WGK): WGK 1
• Point d'éclair (°F): Not applicable
• Point d'éclair (°C): Not applicable