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221759

Sigma-Aldrich

Ammonium cerium(IV) sulfate dihydrate

Synonym(s):

Ceric ammonium sulfate, Cerium(IV) ammonium sulfate

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About This Item

Linear Formula:
Ce(NH4)4(SO4)4 · 2H2O
CAS Number:
10378-47-9
Molecular Weight:
632.55
MDL number:
MFCD00149417
UNSPSC Code:
12352302
PubChem Substance ID:
24853259
NACRES:
NA.23

Assay

≥94.0% (with KMnO4, redox titration)

Quality Level

200

form

powder

composition

Ce(IV), ≥20%

reaction suitability

reagent type: catalyst
core: cerium

mp

130 °C (lit.)

SMILES string

N.N.N.N.O.O.[Ce+4].OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O.OS([O-])(=O)=O

InChI

1S/Ce.4H3N.4H2O4S.2H2O/c;;;;;4*1-5(2,3)4;;/h;4*1H3;4*(H2,1,2,3,4);2*1H2/q+4;;;;;;;;;;/p-4

InChI key

VCNAMBGKEDPVGQ-UHFFFAOYSA-J

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Application

The product may be used to initiate the radical polymerization of pectin-poly(ethylene glycol) methacrylate (PEGMA) supracmolecular hydrogels. Ammonium cerium sulphate impregnated starch may be carbonized to form cerium dispersed carbon (CeDC) sorbent used for the extraction of excess fluoride in drinking water.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
BCCK9880
BCCJ5705
BCCJ5704
MKCQ1791
BCCF1477

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Cerium dispersed in carbon (CeDC) and its adsorption behavior: A first example of tailored adsorbent for fluoride removal from drinking water
Sivasankar V, et al.
Chemical Engineering Journal, 214, 45-54 (2013)
Thixotropic Supramolecular Pectin-Poly (Ethylene Glycol) Methacrylate (PEGMA) Hydrogels.
Chan SY, et al.
Polymer, 8(11), 404-404 (2016)
K H Gordon et al.
Organic letters, 3(1), 53-56 (2001-06-30)
[figure: see text] A novel benzyloxyaniline linker that uses ceric ammonium nitrate (CAN) as a cleavage reagent is described. Its application in the solid-phase synthesis of N-unsubstituted beta-lactams and secondary amides furnishes compounds in moderate to excellent yield (45-91%) and
S Kaul et al.
Amino acids, 34(2), 315-320 (2006-11-07)
An assessment of the potential of proline to scavenge free radicals was made in a couple of in vitro assay systems, namely graft co-polymerization and autooxidation of pyrogallol. Both these assays are essentially dependent upon free radical mechanisms. Graft co-polymerization
Babu G Gowda et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 18(6), 671-674 (2002-06-27)
Two simple and sensitive indirect spectrophotometric methods for the assay of propranolol hydrochloride (PPH) and piroxicam (PX) in pure and pharmaceutical formulations have been proposed. The methods are based on the oxidation of PPH by a known excess of standard
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