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Merck

24308

Supelco

βß-DEX 325

L × I.D. 30 m × 0.25 mm, df 0.25 μm

Synonym(e):

β-DEX 325, 30M .25MM .25UM

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About This Item

UNSPSC-Code:
41115710
eCl@ss:
32119290

Materialien

fused silica

Qualitätsniveau

Beschreibung

GC capillary column

Parameter

30-230 °C temperature

Beta-Wert

250

df

0.25 μm

Methode(n)

gas chromatography (GC): suitable

L × ID

30 m × 0.25 mm

Aktive Matrixgruppe

non-bonded; 25% 2,3-di-O-methyl-6-O-TBDMS-β-cyclodextrin in SPB-20 poly(20% phenyl/80% dimethylsiloxane) phase

Anwendung(en)

agriculture
chemicals and industrial polymers
cleaning products
clinical
cosmetics
environmental
flavors and fragrances
food and beverages
forensics and toxicology
life science and biopharma
personal care
pharmaceutical (small molecule)

Säulenart

capillary chiral

Trenntechnik

chiral

Allgemeine Beschreibung

Phase: nicht gebunden; 25% 2,3-Di-O-acetyl-6-O-TBDMS-β-cyclodextrin in SPB-20 Poly(20% phenyl/80% dimethylsiloxan)

Anwendung

ß-DEX-325 column was used in gas-liquid chromatography (GLC), for determination of (R)-1-O-acetyl-2-ethyl-1,3-propanediol, formed from 2-Ethyl-1,3-propanediol 1 and its related di-O-acetate, by partial chemoenzymatic acetylation and deacetylation, by Pseudomonas fluorescens lipase. ß -Dex-325 capillary column was also used for resolving 8-acetoxylinalool enantiomers, in an experimental study done in order to study the origin of the enantioselectivity in the biosynthesis of the lilac compounds in Actinidia arguta flowers.

Chemische/physikalische Beständigkeit

Temp.grenzen:
  • 30 °C bis 230 °C

Sonstige Hinweise

We offer a variety of chromatography accessories including analytical syringes

Rechtliche Hinweise

DEX is a trademark of Sigma-Aldrich Co. LLC

Anwendung

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Die Dokumentenbibliothek aufrufen

Chiral building-blocks by chemoenzymatic desymmetrization of 2-ethyl-1, 3-propanediol for the preparation of biologically active natural products.
Isidoro I
Tetrahedron Asymmetry, 10 (3), 449-455 (1999)
A J Matich et al.
Phytochemistry, 68(13), 1746-1751 (2007-05-01)
Biosynthesis of lilac compounds in 'Hortgem Tahi' kiwifruit (Actinidia arguta) flowers was investigated by treating inflorescences with d(5)-linalool. The incorporation of the deuterium label into 8-hydroxylinalool, 8-oxolinalool, the lilac aldehydes, alcohols, and alcohol epoxides was followed by GC-MS and enantioselective

Chromatograms

suitable for GC

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