402990

Chloriod

ACS reagent, 1.10±0.1 I/Cl ratio basis

• Synonym(e): Iodmonochlorid
• Lineare Formel: ICl
• CAS-Nummer: 7790-99-0
• Molekulargewicht: 162.36
• EG-Nummer: 232-236-7
• MDL-Nummer: MFCD00011354
• UNSPSC-Code: 12352300
• PubChem Substanz-ID: 329755974
• NACRES: NB.24

Eigenschaften

• Qualität: ACS reagent
• Form: solid or liquid
• Verunreinigungen: ≤0.005% insolubles
• bp: 97.4 °C (lit.)
• Löslichkeit: acetic acid: soluble(lit.); acetone: soluble(lit.); alcohol: soluble(lit.); carbon disulfide: soluble(lit.)
• Dichte: 3.24 g/mL at 25 °C (lit.)
• Lagertemp.: 2-8°C
• SMILES String: ClI
• InChI: 1S/ClI/c1-2
• InChIKey: QZRGKCOWNLSUDK-UHFFFAOYSA-N

Beschreibung

Allgemeine Beschreibung

Iodine monochloride is an interhalogen compound. It forms various complexes with ethyl, isopropyl and t-butylbenzenes. Equilibrium constants for the formation of these complexes have been evaluated. It affords electrically conducting solution on dissolution in polar solvents. Its reaction with thymidine, 3-mono- and 3,3′,5′-trialkylsubstitued thymidine showed that it helps in deglycosylation, anomerization and isomerization of thymidine.

Anwendung

Iodine monochloride (ICl) may be employed for the halogenation of methoxy and dimethoxybenzenes. It may be used for the synthesis of flavones.

Iodine monochloride may be used in the synthesis of the following:

• 2-(4-haloisoquinolin-1-yl)ethanol derivatives
• 5-iodosalicylaldehydes
• 5-aryl-6-iodo-8-phenylpyrazolo[1,5-c]-1,2,4-triazolo[4,3-a]pyrimidines
• (±)-1-cyclohexyl-4-iodo-3-methoxybutan-1-ol
• (±)-4-Iodo-3-methoxy-1-phenylbutan-1-ol

Sicherheitshinweise

• Piktogramme: GHS05,GHS07
• Signalwort: Danger
• H-Sätze: H314,H335
• P-Sätze: P261 - P271 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Gefahreneinstufungen: Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• Zielorgane: Respiratory system
• Lagerklassenschlüssel: 8B - Non-combustible corrosive hazardous materials
• WGK: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable