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Merck

236489

Sigma-Aldrich

Eisen(III)-chlorid Hexahydrat

greener alternative

ACS reagent, 97%

Synonym(e):

Eisenchlorid

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5 G
32,00 €
100 G
40,80 €
500 G
116,00 €
6 X 500 G
497,00 €

32,00 €


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5 G
32,00 €
100 G
40,80 €
500 G
116,00 €
6 X 500 G
497,00 €

About This Item

Lineare Formel:
FeCl3 · 6H2O
CAS-Nummer:
Molekulargewicht:
270.30
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352302
PubChem Substanz-ID:
NACRES:
NA.21
Assay:
97%
97.0-102.0% (ACS specification)
Qualität:
ACS reagent
Form:
chunks

32,00 €


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Qualität

ACS reagent

Qualitätsniveau

Agentur

suitable for SM 5210

Dampfdruck

1 mmHg ( 194 °C)

Assay

97%
97.0-102.0% (ACS specification)

Form

chunks

Eignung der Reaktion

reagent type: catalyst
core: iron

Grünere Alternativprodukt-Eigenschaften

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

Verunreinigungen

≤0.01% P compounds (as PO4)
≤0.01% insolubles
≤0.1% Substances not pptd. by NH4OH (as sulfates)

bp

280-285 °C (lit.)

mp (Schmelzpunkt)

37 °C (lit.)

Anionenspuren

nitrate (NO3-): ≤0.01%
sulfate (SO42-): ≤0.01%

Kationenspuren

Cu: ≤0.003%
Fe2+:, passes test (lim. ~0.002%)
Zn: ≤0.003%

Grünere Alternativprodukt-Kategorie

SMILES String

O.O.O.O.O.O.Cl[Fe](Cl)Cl

InChI

1S/3ClH.Fe.6H2O/h3*1H;;6*1H2/q;;;+3;;;;;;/p-3

InChIKey

NQXWGWZJXJUMQB-UHFFFAOYSA-K

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Allgemeine Beschreibung

Wir verpflichten uns, Ihnen umweltfreundlichere Alternativprodukte anzubieten, die ein oder mehrere der „12 Prinzipien der Grünen Chemie“ erfüllen. Eisenkatalysatoren sind kostengünstig und umweltschonend. Weitere Informationen finden Sie hier.

Anwendung

Eisen(III)-Chlorid-Hexahydrat kann in folgenden Reaktionen als Katalysator eingesetzt werden:
  • Veresterung von Fettsäuren und Alkoholen zur Synthese von Fettsäureestern.
  • Regioselektive Arylierungen von α-Amidosulfonen mit elektronenreichen Arenen zur Synthese von unsymmetrischen oder bisymmetrischen Triarylmethanen über die Friedel-Crafts-Alkylierung.
  • Synthese von Acylazid-Derivaten durch die Acylierung von Natriumazid mit N-Acylbenzotriazolen.

Piktogramme

CorrosionExclamation mark

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 4 Oral - Eye Dam. 1 - Skin Irrit. 2

Lagerklassenschlüssel

13 - Non Combustible Solids

WGK

WGK 1

Flammpunkt (°F)

Not applicable

Flammpunkt (°C)

Not applicable


Hier finden Sie alle aktuellen Versionen:

Analysenzertifikate (COA)

Lot/Batch Number

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Kunden haben sich ebenfalls angesehen

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Lii, K-H. et al.
Chemistry of Materials, 10, 2599-2599 (1998)
Eagleson M.
Concise Encyclopedia Chemistry, 553-553 (1994)

Verwandter Inhalt

This page is intended to make it easier to find the consumables you need based on the analytical method you’re using. Methods included on this page come from the EPA, Standard Methods and ASTM.

Fragen

1-3 von 3 Fragen  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 Antwort
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 Antwort
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  3. How can I calculate the percentage of a specific element in a compound, like the elemental iron in 236489 BCCF3238?

    1 Antwort
    1. The elemental iron in this product can be determined by dividing the molecular weight of iron by the molecular weight of the material, assuming 100% purity. For lot BCCF3238 with a purity of 99.0%, the calculation, taking purity into account, would be: 55.845 g/mol / (270.30 g/mol / 0.99) = ~20.45%. This translates to approximately 204.5 mg of Fe(III) per gram of ferric chloride hexahydrate.

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